In situ Polymerization Technique for Obtaining Composite Materials Based on Polyethylene, Multi-walled Carbon Nanotubes and Cobalt Nanoparticles

• Published in: Russian journal of applied chemistry 2018, Vol.91 (1), p.127-135
• Main Authors: Kazakova, M. A., Semikolenova, N. V., Korovin, E. Yu, Moseenkov, S. I., Andreev, A. S., Kachalov, A. S., Kuznetsov, V. L., Suslyaev, V. I., Mats’ko, M. A., Zakharov, V. A.
• Format: Article
• Language: English
• Subjects: Antistatics; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Cobalt; Composite materials; Electrical resistivity; Electromagnetic radiation; Industrial Chemistry/Chemical Engineering; Macromolecular Compounds and Polymeric Materials; Multi wall carbon nanotubes; Nanoparticles; Nanotubes; Polyethylene; Polyethylenes; Polymer matrix composites; Polymerization; Protective coatings
• ISSN: 1070-4272; 1608-3296
• DOI: 10.1134/S1070427218010202

Specific features of formation of composite materials based on polyethylene, multi-walled carbon nanotubes, and cobalt nanoparticles (MWCNT–PE and Co/MWCNT–PE) by in situ polymerization were revealed. The in situ polymerization technique is based on ethylene polymerization on a highly dispersed Ti-containing catalyst supported on the surface of MWCNT and Со/MWCNT. This method ensures uniform distribution of MWCNT and Co/MWCNT in the polyethylene matrix. The effect of MWCNT and Со/MWCNT on the final properties of the composite materials was determined. Introduction of MWCNT into the polyethylene matrix increases the specific electrical conductivity of the material. Such composite materials can be used for preparing concentrates with preset composition for the subsequent preparation of antistatic coatings. Introduction of the Со/MWCNT filler into the polyethylene matrix makes the material paramagnetic owing to Co nanoparticles and allows its use for preparing coatings that efficiently protect from electromagnetic radiation.