Loading…
Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures
Cobalt antimonate (CoSb 2 O 6 ) nanostructures were prepared using the microwave-assisted colloidal method, employing cobalt nitrate, antimony chloride, ethylenediamine and ethyl alcohol. The solvent was evaporated through microwave radiation at 140 W. The precursor material was dried at 200 °C and...
Saved in:
| Published in: | Journal of materials science. Materials in electronics 2018-09, Vol.29 (18), p.15632-15642 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43 |
| container_end_page | 15642 |
| container_issue | 18 |
| container_start_page | 15632 |
| container_title | Journal of materials science. Materials in electronics |
| container_volume | 29 |
| creator | Guillén-Bonilla, Alex Blanco-Alonso, Oscar Guillén-Bonilla, José Trinidad de la Luz Olvera-Amador, M. Rodríguez-Betancourtt, Verónica M. Sánchez-Martínez, Araceli Morán-Lázaro, Juan Pablo Martínez-García, Mario Guillén-Bonilla, Héctor |
| description | Cobalt antimonate (CoSb
2
O
6
) nanostructures were prepared using the microwave-assisted colloidal method, employing cobalt nitrate, antimony chloride, ethylenediamine and ethyl alcohol. The solvent was evaporated through microwave radiation at 140 W. The precursor material was dried at 200 °C and then calcined at 300, 400, 500, and 600 °C in static air. The crystalline phase of the material was found at 600 °C by means of X-ray diffraction. Morphology was analyzed through scanning electron microscopy, finding octahedral particles with an edge length between 3 and 50 µm, and other particles of nanometric size. The size of these irregularly shaped nanoparticles was estimated of ~ 17.6 nm by means of transmission electron microscopy. UV–vis analyses of semiconducting powders revealed a forbidden band of ~ 1.82 eV. For the gas detection experiments, thick films and pellets were made of CoSb
2
O
6
powders (600 °C). The tests were carried out in air, CO, and CO
2
atmospheres at different gas concentrations and operating temperatures. The cobalt antimonate nanoparticles showed high sensitivity at 300 °C and 300 ppm of CO, and a good dynamic response at 100 ppm of CO
2
. |
| doi_str_mv | 10.1007/s10854-018-9157-2 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2031165260</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2031165260</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43</originalsourceid><addsrcrecordid>eNp1kE9LAzEUxIMoWKsfwFvA8-pLsmm2R1n8B4UeVPAWsrtv7ZY2WZMsUu9-b9Ou4MnTwJvfzIMh5JLBNQNQN4FBIfMMWJHNmVQZPyKTpCLLC_52TCYwT8dccn5KzkJYA8AsF8WEfD_vbFxh6AI1tqH1ynhTR_Tdl4mds9S1tHaV2cRkx27rrIlIrbEuRD_UcfA4BlNH52mIQ7OjJtDeRUy82dByefDLJacBbXCemkg37pNG3PbozaHinJy0ZhPw4len5PX-7qV8zBbLh6fydpHVQoqYFXOhZFO1smjbnBWqkgiNUdCoimEOolI5U0rwCoUsEOYoeVVjDUwohqLKxZRcjb29dx8DhqjXbvA2vdQcBGMzyWeQKDZStXcheGx177ut8TvNQO_X1uPaOq2t92trnjJ8zITE2nf0f83_h34Au36ElA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2031165260</pqid></control><display><type>article</type><title>Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures</title><source>Springer Nature</source><creator>Guillén-Bonilla, Alex ; Blanco-Alonso, Oscar ; Guillén-Bonilla, José Trinidad ; de la Luz Olvera-Amador, M. ; Rodríguez-Betancourtt, Verónica M. ; Sánchez-Martínez, Araceli ; Morán-Lázaro, Juan Pablo ; Martínez-García, Mario ; Guillén-Bonilla, Héctor</creator><creatorcontrib>Guillén-Bonilla, Alex ; Blanco-Alonso, Oscar ; Guillén-Bonilla, José Trinidad ; de la Luz Olvera-Amador, M. ; Rodríguez-Betancourtt, Verónica M. ; Sánchez-Martínez, Araceli ; Morán-Lázaro, Juan Pablo ; Martínez-García, Mario ; Guillén-Bonilla, Héctor</creatorcontrib><description>Cobalt antimonate (CoSb
2
O
6
) nanostructures were prepared using the microwave-assisted colloidal method, employing cobalt nitrate, antimony chloride, ethylenediamine and ethyl alcohol. The solvent was evaporated through microwave radiation at 140 W. The precursor material was dried at 200 °C and then calcined at 300, 400, 500, and 600 °C in static air. The crystalline phase of the material was found at 600 °C by means of X-ray diffraction. Morphology was analyzed through scanning electron microscopy, finding octahedral particles with an edge length between 3 and 50 µm, and other particles of nanometric size. The size of these irregularly shaped nanoparticles was estimated of ~ 17.6 nm by means of transmission electron microscopy. UV–vis analyses of semiconducting powders revealed a forbidden band of ~ 1.82 eV. For the gas detection experiments, thick films and pellets were made of CoSb
2
O
6
powders (600 °C). The tests were carried out in air, CO, and CO
2
atmospheres at different gas concentrations and operating temperatures. The cobalt antimonate nanoparticles showed high sensitivity at 300 °C and 300 ppm of CO, and a good dynamic response at 100 ppm of CO
2
.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-018-9157-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Antimony ; Carbon dioxide ; Carbon monoxide ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Cobalt ; Dynamic response ; Ethanol ; Ethylenediamine ; Low temperature ; Materials Science ; Microwaves ; Nanoparticles ; Nanostructure ; Optical and Electronic Materials ; Scanning electron microscopy ; Thick films ; Transmission electron microscopy ; X-ray diffraction</subject><ispartof>Journal of materials science. Materials in electronics, 2018-09, Vol.29 (18), p.15632-15642</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43</citedby><cites>FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Guillén-Bonilla, Alex</creatorcontrib><creatorcontrib>Blanco-Alonso, Oscar</creatorcontrib><creatorcontrib>Guillén-Bonilla, José Trinidad</creatorcontrib><creatorcontrib>de la Luz Olvera-Amador, M.</creatorcontrib><creatorcontrib>Rodríguez-Betancourtt, Verónica M.</creatorcontrib><creatorcontrib>Sánchez-Martínez, Araceli</creatorcontrib><creatorcontrib>Morán-Lázaro, Juan Pablo</creatorcontrib><creatorcontrib>Martínez-García, Mario</creatorcontrib><creatorcontrib>Guillén-Bonilla, Héctor</creatorcontrib><title>Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Cobalt antimonate (CoSb
2
O
6
) nanostructures were prepared using the microwave-assisted colloidal method, employing cobalt nitrate, antimony chloride, ethylenediamine and ethyl alcohol. The solvent was evaporated through microwave radiation at 140 W. The precursor material was dried at 200 °C and then calcined at 300, 400, 500, and 600 °C in static air. The crystalline phase of the material was found at 600 °C by means of X-ray diffraction. Morphology was analyzed through scanning electron microscopy, finding octahedral particles with an edge length between 3 and 50 µm, and other particles of nanometric size. The size of these irregularly shaped nanoparticles was estimated of ~ 17.6 nm by means of transmission electron microscopy. UV–vis analyses of semiconducting powders revealed a forbidden band of ~ 1.82 eV. For the gas detection experiments, thick films and pellets were made of CoSb
2
O
6
powders (600 °C). The tests were carried out in air, CO, and CO
2
atmospheres at different gas concentrations and operating temperatures. The cobalt antimonate nanoparticles showed high sensitivity at 300 °C and 300 ppm of CO, and a good dynamic response at 100 ppm of CO
2
.</description><subject>Antimony</subject><subject>Carbon dioxide</subject><subject>Carbon monoxide</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Dynamic response</subject><subject>Ethanol</subject><subject>Ethylenediamine</subject><subject>Low temperature</subject><subject>Materials Science</subject><subject>Microwaves</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Optical and Electronic Materials</subject><subject>Scanning electron microscopy</subject><subject>Thick films</subject><subject>Transmission electron microscopy</subject><subject>X-ray diffraction</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEUxIMoWKsfwFvA8-pLsmm2R1n8B4UeVPAWsrtv7ZY2WZMsUu9-b9Ou4MnTwJvfzIMh5JLBNQNQN4FBIfMMWJHNmVQZPyKTpCLLC_52TCYwT8dccn5KzkJYA8AsF8WEfD_vbFxh6AI1tqH1ynhTR_Tdl4mds9S1tHaV2cRkx27rrIlIrbEuRD_UcfA4BlNH52mIQ7OjJtDeRUy82dByefDLJacBbXCemkg37pNG3PbozaHinJy0ZhPw4len5PX-7qV8zBbLh6fydpHVQoqYFXOhZFO1smjbnBWqkgiNUdCoimEOolI5U0rwCoUsEOYoeVVjDUwohqLKxZRcjb29dx8DhqjXbvA2vdQcBGMzyWeQKDZStXcheGx177ut8TvNQO_X1uPaOq2t92trnjJ8zITE2nf0f83_h34Au36ElA</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Guillén-Bonilla, Alex</creator><creator>Blanco-Alonso, Oscar</creator><creator>Guillén-Bonilla, José Trinidad</creator><creator>de la Luz Olvera-Amador, M.</creator><creator>Rodríguez-Betancourtt, Verónica M.</creator><creator>Sánchez-Martínez, Araceli</creator><creator>Morán-Lázaro, Juan Pablo</creator><creator>Martínez-García, Mario</creator><creator>Guillén-Bonilla, Héctor</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope></search><sort><creationdate>20180901</creationdate><title>Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures</title><author>Guillén-Bonilla, Alex ; Blanco-Alonso, Oscar ; Guillén-Bonilla, José Trinidad ; de la Luz Olvera-Amador, M. ; Rodríguez-Betancourtt, Verónica M. ; Sánchez-Martínez, Araceli ; Morán-Lázaro, Juan Pablo ; Martínez-García, Mario ; Guillén-Bonilla, Héctor</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Antimony</topic><topic>Carbon dioxide</topic><topic>Carbon monoxide</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Dynamic response</topic><topic>Ethanol</topic><topic>Ethylenediamine</topic><topic>Low temperature</topic><topic>Materials Science</topic><topic>Microwaves</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Optical and Electronic Materials</topic><topic>Scanning electron microscopy</topic><topic>Thick films</topic><topic>Transmission electron microscopy</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guillén-Bonilla, Alex</creatorcontrib><creatorcontrib>Blanco-Alonso, Oscar</creatorcontrib><creatorcontrib>Guillén-Bonilla, José Trinidad</creatorcontrib><creatorcontrib>de la Luz Olvera-Amador, M.</creatorcontrib><creatorcontrib>Rodríguez-Betancourtt, Verónica M.</creatorcontrib><creatorcontrib>Sánchez-Martínez, Araceli</creatorcontrib><creatorcontrib>Morán-Lázaro, Juan Pablo</creatorcontrib><creatorcontrib>Martínez-García, Mario</creatorcontrib><creatorcontrib>Guillén-Bonilla, Héctor</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guillén-Bonilla, Alex</au><au>Blanco-Alonso, Oscar</au><au>Guillén-Bonilla, José Trinidad</au><au>de la Luz Olvera-Amador, M.</au><au>Rodríguez-Betancourtt, Verónica M.</au><au>Sánchez-Martínez, Araceli</au><au>Morán-Lázaro, Juan Pablo</au><au>Martínez-García, Mario</au><au>Guillén-Bonilla, Héctor</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2018-09-01</date><risdate>2018</risdate><volume>29</volume><issue>18</issue><spage>15632</spage><epage>15642</epage><pages>15632-15642</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Cobalt antimonate (CoSb
2
O
6
) nanostructures were prepared using the microwave-assisted colloidal method, employing cobalt nitrate, antimony chloride, ethylenediamine and ethyl alcohol. The solvent was evaporated through microwave radiation at 140 W. The precursor material was dried at 200 °C and then calcined at 300, 400, 500, and 600 °C in static air. The crystalline phase of the material was found at 600 °C by means of X-ray diffraction. Morphology was analyzed through scanning electron microscopy, finding octahedral particles with an edge length between 3 and 50 µm, and other particles of nanometric size. The size of these irregularly shaped nanoparticles was estimated of ~ 17.6 nm by means of transmission electron microscopy. UV–vis analyses of semiconducting powders revealed a forbidden band of ~ 1.82 eV. For the gas detection experiments, thick films and pellets were made of CoSb
2
O
6
powders (600 °C). The tests were carried out in air, CO, and CO
2
atmospheres at different gas concentrations and operating temperatures. The cobalt antimonate nanoparticles showed high sensitivity at 300 °C and 300 ppm of CO, and a good dynamic response at 100 ppm of CO
2
.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-018-9157-2</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2018-09, Vol.29 (18), p.15632-15642 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_2031165260 |
| source | Springer Nature |
| subjects | Antimony Carbon dioxide Carbon monoxide Characterization and Evaluation of Materials Chemistry and Materials Science Cobalt Dynamic response Ethanol Ethylenediamine Low temperature Materials Science Microwaves Nanoparticles Nanostructure Optical and Electronic Materials Scanning electron microscopy Thick films Transmission electron microscopy X-ray diffraction |
| title | Synthesis and characterization of cobalt antimonate nanostructures and their study as potential CO and CO2 sensor at low temperatures |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-14T11%3A09%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20characterization%20of%20cobalt%20antimonate%20nanostructures%20and%20their%20study%20as%20potential%20CO%20and%20CO2%20sensor%20at%20low%20temperatures&rft.jtitle=Journal%20of%20materials%20science.%20Materials%20in%20electronics&rft.au=Guill%C3%A9n-Bonilla,%20Alex&rft.date=2018-09-01&rft.volume=29&rft.issue=18&rft.spage=15632&rft.epage=15642&rft.pages=15632-15642&rft.issn=0957-4522&rft.eissn=1573-482X&rft_id=info:doi/10.1007/s10854-018-9157-2&rft_dat=%3Cproquest_cross%3E2031165260%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c353t-89375dbf58ff4187b5e0da70d7b1e403b7417732be358e09e52bcec01371e3b43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2031165260&rft_id=info:pmid/&rfr_iscdi=true |