A dimeric cobalt(II)-suberate complex with 3-amino­pyridine

The title complex, μ‐octane‐1,8‐dioato‐bis[bis(3‐aminopyridine)chloro(methanol)cobalt(II)], [Co2(C8H12O4)Cl2(C5H6N2)4(CH4O)2], is located on a crystallographic centre of inversion. The coordination around each of the Co centres is distorted octa­hedral, involving two N, three O and one Cl atom. Disc...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-11, Vol.62 (11), p.m550-m552
Main Authors: Lah, Nina, Leban, Ivan
Format: Article
Language:English
Subjects:
Chemical compounds
Cobalt
Crystallography
Hydrogen bonds
Online Access:Get full text
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Summary:The title complex, μ‐octane‐1,8‐dioato‐bis[bis(3‐aminopyridine)chloro(methanol)cobalt(II)], [Co2(C8H12O4)Cl2(C5H6N2)4(CH4O)2], is located on a crystallographic centre of inversion. The coordination around each of the Co centres is distorted octa­hedral, involving two N, three O and one Cl atom. Discrete dimers are connected in a three‐dimensional arrangement through N—H⋯O, N—H⋯Cl and O—H⋯O hydrogen‐bond inter­actions.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270106040935