Fe‐catalyzed dithiane radical induced C−S bond activation−addition to α, β‐unsaturated ketones

An efficient and clean strategy to construct organosulfur compounds has been developed via a Fe‐catalyzed dithiane C−S bond activation/addition process with α, β‐unsaturated ketones. This C−S activation protocol exhibits excellent reactivities, and up to 92% yield of the corresponding thioether‐thio...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2018-05, Vol.360 (9), p.1795-1799
Main Authors: Min, Deng, Yuan, Xinyu, Liu, Teng, Liu, Jian, Tang, Shouchu
Format: Article
Language:English
Subjects:
Activation
Conjugates
C−S Addition
Dithiane
Iron
Ketones
Organosulfur Compounds
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Summary:An efficient and clean strategy to construct organosulfur compounds has been developed via a Fe‐catalyzed dithiane C−S bond activation/addition process with α, β‐unsaturated ketones. This C−S activation protocol exhibits excellent reactivities, and up to 92% yield of the corresponding thioether‐thioester derivatives could be obtained under the mild conditions, allowing the ready preparation of a number of synthetically valuable S‐linked conjugates.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800241