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Observation of current rectification by a new asymmetric iron() surfactant in a eutectic GaIn|LB monolayer|Au sandwich
In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [Fe III (L N 3 O )(OMe) 2 ], where (L N 3 O ) − is the deprotonated form of the new asymmetric ligand 2-(( E )-((4,5-bis(2-methoxyethoxy)-2-((( E )-pyridin-2-ylmethyl...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2018-05, Vol.47 (18), p.6344-635 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c182a-ee7b15b915a54f990cd5f12da6fb8e5e4bd2f66deceab88e483540db86f714b63 |
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| cites | cdi_FETCH-LOGICAL-c182a-ee7b15b915a54f990cd5f12da6fb8e5e4bd2f66deceab88e483540db86f714b63 |
| container_end_page | 635 |
| container_issue | 18 |
| container_start_page | 6344 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 47 |
| creator | Johnson, Marcus S Horton, Chad L Gonawala, Sunalee Verani, Cláudio N Metzger, Robert M |
| description | In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [Fe
III
(L
N
3
O
)(OMe)
2
], where (L
N
3
O
)
−
is the deprotonated form of the new asymmetric ligand 2-((
E
)-((4,5-bis(2-methoxyethoxy)-2-(((
E
)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-
tert
-butyl-phenol. This species rectifies current when deposited as a Langmuir-Blodget film in a "EGaIn/Ga
2
O
3
|LB|Au" sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.
This surfactant, as a Langmuir-Blodgett monolayer on Au, has electrical rectification ratios from 25 to 300 at 1 Volt (the coordinating Ns are the electron donors, Fe(
iii
) is the electron acceptor). The red arrow shows the direction of preferred electron current. |
| doi_str_mv | 10.1039/c8dt00562a |
| format | article |
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III
(L
N
3
O
)(OMe)
2
], where (L
N
3
O
)
−
is the deprotonated form of the new asymmetric ligand 2-((
E
)-((4,5-bis(2-methoxyethoxy)-2-(((
E
)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-
tert
-butyl-phenol. This species rectifies current when deposited as a Langmuir-Blodget film in a "EGaIn/Ga
2
O
3
|LB|Au" sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.
This surfactant, as a Langmuir-Blodgett monolayer on Au, has electrical rectification ratios from 25 to 300 at 1 Volt (the coordinating Ns are the electron donors, Fe(
iii
) is the electron acceptor). The red arrow shows the direction of preferred electron current.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt00562a</identifier><identifier>PMID: 29633775</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Gallium oxides ; Gold ; Langmuir-Blodgett films ; Molecular chains ; Rectifiers</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018-05, Vol.47 (18), p.6344-635</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c182a-ee7b15b915a54f990cd5f12da6fb8e5e4bd2f66deceab88e483540db86f714b63</citedby><cites>FETCH-LOGICAL-c182a-ee7b15b915a54f990cd5f12da6fb8e5e4bd2f66deceab88e483540db86f714b63</cites><orcidid>0000-0001-6482-1738 ; 0000-0002-1833-5461</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29633775$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Johnson, Marcus S</creatorcontrib><creatorcontrib>Horton, Chad L</creatorcontrib><creatorcontrib>Gonawala, Sunalee</creatorcontrib><creatorcontrib>Verani, Cláudio N</creatorcontrib><creatorcontrib>Metzger, Robert M</creatorcontrib><title>Observation of current rectification by a new asymmetric iron() surfactant in a eutectic GaIn|LB monolayer|Au sandwich</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [Fe
III
(L
N
3
O
)(OMe)
2
], where (L
N
3
O
)
−
is the deprotonated form of the new asymmetric ligand 2-((
E
)-((4,5-bis(2-methoxyethoxy)-2-(((
E
)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-
tert
-butyl-phenol. This species rectifies current when deposited as a Langmuir-Blodget film in a "EGaIn/Ga
2
O
3
|LB|Au" sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.
This surfactant, as a Langmuir-Blodgett monolayer on Au, has electrical rectification ratios from 25 to 300 at 1 Volt (the coordinating Ns are the electron donors, Fe(
iii
) is the electron acceptor). The red arrow shows the direction of preferred electron current.</description><subject>Gallium oxides</subject><subject>Gold</subject><subject>Langmuir-Blodgett films</subject><subject>Molecular chains</subject><subject>Rectifiers</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpd0U1LAzEQBuAgitXqxbsS8KJCNR-b7O6x1k8oeKnnJclOMNJNNNlVCv54t7ZW8JIE5plhyIvQESWXlPDyyhR1S4iQTG2hPZrl-ahkPNvevJkcoP2UXglhjAi2iwaslJznudhDH086QfxQrQseB4tNFyP4FkcwrbPOrAp6gRX28IlVWjQNtNEZ7GLwZ-c4ddEq06q-x_leQdcuWw2-V4_-a3qNm-DDXC0gfo07nJSvP515OUA7Vs0THK7vIXq-u51NHkbTp_vHyXg6MrRgagSQayp0SYUSmS1LYmphKauVtLoAAZmumZWyBgNKFwVkBRcZqXUhbU4zLfkQna3mvsXw3kFqq8YlA_O58hC6VDHCeM5Ef_T09B99DV30_Xa94pJTycqlulgpE0NKEWz1Fl2j4qKipFqmUU2Km9lPGuMen6xHdrqBekN_v78HxysQk9lU_-Lk30d_kC8</recordid><startdate>20180508</startdate><enddate>20180508</enddate><creator>Johnson, Marcus S</creator><creator>Horton, Chad L</creator><creator>Gonawala, Sunalee</creator><creator>Verani, Cláudio N</creator><creator>Metzger, Robert M</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6482-1738</orcidid><orcidid>https://orcid.org/0000-0002-1833-5461</orcidid></search><sort><creationdate>20180508</creationdate><title>Observation of current rectification by a new asymmetric iron() surfactant in a eutectic GaIn|LB monolayer|Au sandwich</title><author>Johnson, Marcus S ; Horton, Chad L ; Gonawala, Sunalee ; Verani, Cláudio N ; Metzger, Robert M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c182a-ee7b15b915a54f990cd5f12da6fb8e5e4bd2f66deceab88e483540db86f714b63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Gallium oxides</topic><topic>Gold</topic><topic>Langmuir-Blodgett films</topic><topic>Molecular chains</topic><topic>Rectifiers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Johnson, Marcus S</creatorcontrib><creatorcontrib>Horton, Chad L</creatorcontrib><creatorcontrib>Gonawala, Sunalee</creatorcontrib><creatorcontrib>Verani, Cláudio N</creatorcontrib><creatorcontrib>Metzger, Robert M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Johnson, Marcus S</au><au>Horton, Chad L</au><au>Gonawala, Sunalee</au><au>Verani, Cláudio N</au><au>Metzger, Robert M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Observation of current rectification by a new asymmetric iron() surfactant in a eutectic GaIn|LB monolayer|Au sandwich</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018-05-08</date><risdate>2018</risdate><volume>47</volume><issue>18</issue><spage>6344</spage><epage>635</epage><pages>6344-635</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>In this paper we expand on the search for molecular rectifiers of electrical current and report on a hexacoordinate metallosurfactant [Fe
III
(L
N
3
O
)(OMe)
2
], where (L
N
3
O
)
−
is the deprotonated form of the new asymmetric ligand 2-((
E
)-((4,5-bis(2-methoxyethoxy)-2-(((
E
)-pyridin-2-ylmethylene)amino)phenyl)imino)methyl)-4,6-di-
tert
-butyl-phenol. This species rectifies current when deposited as a Langmuir-Blodget film in a "EGaIn/Ga
2
O
3
|LB|Au" sandwich with rectification ratios ranging from 25 to 300 at 1 Volt.
This surfactant, as a Langmuir-Blodgett monolayer on Au, has electrical rectification ratios from 25 to 300 at 1 Volt (the coordinating Ns are the electron donors, Fe(
iii
) is the electron acceptor). The red arrow shows the direction of preferred electron current.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>29633775</pmid><doi>10.1039/c8dt00562a</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-6482-1738</orcidid><orcidid>https://orcid.org/0000-0002-1833-5461</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018-05, Vol.47 (18), p.6344-635 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_journals_2036316297 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Gallium oxides Gold Langmuir-Blodgett films Molecular chains Rectifiers |
| title | Observation of current rectification by a new asymmetric iron() surfactant in a eutectic GaIn|LB monolayer|Au sandwich |
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