Characterization of polymer inclusion membranes (PIM) containing phosphonium ionic liquids and their application for separation of Zn(II) from Fe(III)

BACKGROUND Hydrometallurgical separation of Zn(II) from Fe(III) from HCl solutions is an important issue to regenerate spent effluents. Polymer inclusion membranes (PIMs) are an attractive technique for selective separation and concentration of low concentrated target metal ions, as an alternative t...

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Published in:Journal of chemical technology and biotechnology (1986) 2018-06, Vol.93 (6), p.1767-1777
Main Authors: Baczyńska, Monika, Słomka, Żaneta, Rzelewska, Martyna, Waszak, Michał, Nowicki, Marek, Regel‐Rosocka, Magdalena
Format: Article
Language:English
Subjects:
Atomic force microscopy
Cellulose
Cellulosic resins
Contact angle
Hydrometallurgy
Image contrast
Ionic liquids
Ions
Iron
iron(III)
Mechanical properties
membrane ageing
Membranes
Metal concentrations
Metal ions
Microscopy
Nanoindentation
Phase contrast
polymer inclusion membrane (PIM)
Polymers
Powder injection molding
Scanning electron microscopy
Separation
Zinc
zinc(II)
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cited_by cdi_FETCH-LOGICAL-c3342-56ce7b627b3175089f4040e9b0b805885685535b9cd7af1a7b0198a4a8ea52a23
cites cdi_FETCH-LOGICAL-c3342-56ce7b627b3175089f4040e9b0b805885685535b9cd7af1a7b0198a4a8ea52a23
container_end_page 1777
container_issue 6
container_start_page 1767
container_title Journal of chemical technology and biotechnology (1986)
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creator Baczyńska, Monika
Słomka, Żaneta
Rzelewska, Martyna
Waszak, Michał
Nowicki, Marek
Regel‐Rosocka, Magdalena
description BACKGROUND Hydrometallurgical separation of Zn(II) from Fe(III) from HCl solutions is an important issue to regenerate spent effluents. Polymer inclusion membranes (PIMs) are an attractive technique for selective separation and concentration of low concentrated target metal ions, as an alternative to liquid–liquid extraction. RESULTS PIMs containing phosphonium ionic liquids trihexyl(tetradecyl)phosphonium chloride (Cyphos IL101) or bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL104), as metal ion carriers, o‐nitrophenyloctyl ether (NPOE) as a plasticizer and triacetate cellulose (CTA) as a polymer matrix were prepared and characterized by contact angle measurements, scanning electron microscopy, atomic force microscopy and nanoindentation measurements. An important aspect was to determine the influence of PIMs ageing on their morphology and efficiency of Zn(II) transport. Finally, PIMs were applied for separation of Zn(II) from Fe(III). CONCLUSION The surface of the IL‐containing PIMs was characterized as hydrophilic, rough, without apparent pores. However, phase contrast images indicated that the plasticized membranes were not fully homogeneous. Stability of the PIMs, particularly of those without the plasticizer or without the carrier, is affected by ageing. Finally, a membrane‐based successful separation of Zn(II) from Fe(III) was developed with 1 mol L‐1 HCl as a stripping phase for Fe(III), while the majority of Zn(II) were retained in the feed phase (SFe(III)/Zn(II) = 8.85). © 2017 Society of Chemical Industry
doi_str_mv 10.1002/jctb.5552
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Polymer inclusion membranes (PIMs) are an attractive technique for selective separation and concentration of low concentrated target metal ions, as an alternative to liquid–liquid extraction. RESULTS PIMs containing phosphonium ionic liquids trihexyl(tetradecyl)phosphonium chloride (Cyphos IL101) or bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL104), as metal ion carriers, o‐nitrophenyloctyl ether (NPOE) as a plasticizer and triacetate cellulose (CTA) as a polymer matrix were prepared and characterized by contact angle measurements, scanning electron microscopy, atomic force microscopy and nanoindentation measurements. An important aspect was to determine the influence of PIMs ageing on their morphology and efficiency of Zn(II) transport. Finally, PIMs were applied for separation of Zn(II) from Fe(III). CONCLUSION The surface of the IL‐containing PIMs was characterized as hydrophilic, rough, without apparent pores. However, phase contrast images indicated that the plasticized membranes were not fully homogeneous. Stability of the PIMs, particularly of those without the plasticizer or without the carrier, is affected by ageing. Finally, a membrane‐based successful separation of Zn(II) from Fe(III) was developed with 1 mol L‐1 HCl as a stripping phase for Fe(III), while the majority of Zn(II) were retained in the feed phase (SFe(III)/Zn(II) = 8.85). © 2017 Society of Chemical Industry</description><identifier>ISSN: 0268-2575</identifier><identifier>EISSN: 1097-4660</identifier><identifier>DOI: 10.1002/jctb.5552</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>Atomic force microscopy ; Cellulose ; Cellulosic resins ; Contact angle ; Hydrometallurgy ; Image contrast ; Ionic liquids ; Ions ; Iron ; iron(III) ; Mechanical properties ; membrane ageing ; Membranes ; Metal concentrations ; Metal ions ; Microscopy ; Nanoindentation ; Phase contrast ; polymer inclusion membrane (PIM) ; Polymers ; Powder injection molding ; Scanning electron microscopy ; Separation ; Zinc ; zinc(II)</subject><ispartof>Journal of chemical technology and biotechnology (1986), 2018-06, Vol.93 (6), p.1767-1777</ispartof><rights>2017 Society of Chemical Industry</rights><rights>Copyright © 2018 Society of Chemical Industry</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3342-56ce7b627b3175089f4040e9b0b805885685535b9cd7af1a7b0198a4a8ea52a23</citedby><cites>FETCH-LOGICAL-c3342-56ce7b627b3175089f4040e9b0b805885685535b9cd7af1a7b0198a4a8ea52a23</cites><orcidid>0000-0002-4610-760X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Baczyńska, Monika</creatorcontrib><creatorcontrib>Słomka, Żaneta</creatorcontrib><creatorcontrib>Rzelewska, Martyna</creatorcontrib><creatorcontrib>Waszak, Michał</creatorcontrib><creatorcontrib>Nowicki, Marek</creatorcontrib><creatorcontrib>Regel‐Rosocka, Magdalena</creatorcontrib><title>Characterization of polymer inclusion membranes (PIM) containing phosphonium ionic liquids and their application for separation of Zn(II) from Fe(III)</title><title>Journal of chemical technology and biotechnology (1986)</title><description>BACKGROUND Hydrometallurgical separation of Zn(II) from Fe(III) from HCl solutions is an important issue to regenerate spent effluents. Polymer inclusion membranes (PIMs) are an attractive technique for selective separation and concentration of low concentrated target metal ions, as an alternative to liquid–liquid extraction. RESULTS PIMs containing phosphonium ionic liquids trihexyl(tetradecyl)phosphonium chloride (Cyphos IL101) or bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL104), as metal ion carriers, o‐nitrophenyloctyl ether (NPOE) as a plasticizer and triacetate cellulose (CTA) as a polymer matrix were prepared and characterized by contact angle measurements, scanning electron microscopy, atomic force microscopy and nanoindentation measurements. An important aspect was to determine the influence of PIMs ageing on their morphology and efficiency of Zn(II) transport. Finally, PIMs were applied for separation of Zn(II) from Fe(III). CONCLUSION The surface of the IL‐containing PIMs was characterized as hydrophilic, rough, without apparent pores. However, phase contrast images indicated that the plasticized membranes were not fully homogeneous. Stability of the PIMs, particularly of those without the plasticizer or without the carrier, is affected by ageing. Finally, a membrane‐based successful separation of Zn(II) from Fe(III) was developed with 1 mol L‐1 HCl as a stripping phase for Fe(III), while the majority of Zn(II) were retained in the feed phase (SFe(III)/Zn(II) = 8.85). © 2017 Society of Chemical Industry</description><subject>Atomic force microscopy</subject><subject>Cellulose</subject><subject>Cellulosic resins</subject><subject>Contact angle</subject><subject>Hydrometallurgy</subject><subject>Image contrast</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Iron</subject><subject>iron(III)</subject><subject>Mechanical properties</subject><subject>membrane ageing</subject><subject>Membranes</subject><subject>Metal concentrations</subject><subject>Metal ions</subject><subject>Microscopy</subject><subject>Nanoindentation</subject><subject>Phase contrast</subject><subject>polymer inclusion membrane (PIM)</subject><subject>Polymers</subject><subject>Powder injection molding</subject><subject>Scanning electron microscopy</subject><subject>Separation</subject><subject>Zinc</subject><subject>zinc(II)</subject><issn>0268-2575</issn><issn>1097-4660</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqUw8A8ssbRD2osTO84IFYWgIhjKwhI5rkNdJXawE6HyQ_i9JBRGhtOdnr57T3oIXYYwCwHIfCfbYkYpJUdoFEKaBDFjcIxGQBgPCE3oKTrzfgcAjBM2Ql-LrXBCtsrpT9Fqa7AtcWOrfa0c1kZWnR_EWtWFE0Z5PHnOHqdYWtMKbbR5w83W-n6M7mrco1riSr93euOxMBvcbpV2WDRNpeXBv7QOe9X0qX9xr2aSZVNcOlvjpervbHqOTkpReXXxu8foZXm7XtwHq6e7bHG9CmQUxSSgTKqkYCQpojChwNMyhhhUWkDBgXJOGac0okUqN4koQ5EUEKZcxIIrQYkg0RhdHXwbZ9875dt8Zztn-sicQMSSmFOIe2p6oKSz3jtV5o3TtXD7PIR8qD0fas-H2nt2fmA_dKX2_4P5w2J98_PxDVhWhU8</recordid><startdate>201806</startdate><enddate>201806</enddate><creator>Baczyńska, Monika</creator><creator>Słomka, Żaneta</creator><creator>Rzelewska, Martyna</creator><creator>Waszak, Michał</creator><creator>Nowicki, Marek</creator><creator>Regel‐Rosocka, Magdalena</creator><general>John Wiley &amp; 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Polymer inclusion membranes (PIMs) are an attractive technique for selective separation and concentration of low concentrated target metal ions, as an alternative to liquid–liquid extraction. RESULTS PIMs containing phosphonium ionic liquids trihexyl(tetradecyl)phosphonium chloride (Cyphos IL101) or bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL104), as metal ion carriers, o‐nitrophenyloctyl ether (NPOE) as a plasticizer and triacetate cellulose (CTA) as a polymer matrix were prepared and characterized by contact angle measurements, scanning electron microscopy, atomic force microscopy and nanoindentation measurements. An important aspect was to determine the influence of PIMs ageing on their morphology and efficiency of Zn(II) transport. Finally, PIMs were applied for separation of Zn(II) from Fe(III). CONCLUSION The surface of the IL‐containing PIMs was characterized as hydrophilic, rough, without apparent pores. However, phase contrast images indicated that the plasticized membranes were not fully homogeneous. Stability of the PIMs, particularly of those without the plasticizer or without the carrier, is affected by ageing. Finally, a membrane‐based successful separation of Zn(II) from Fe(III) was developed with 1 mol L‐1 HCl as a stripping phase for Fe(III), while the majority of Zn(II) were retained in the feed phase (SFe(III)/Zn(II) = 8.85). © 2017 Society of Chemical Industry</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/jctb.5552</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-4610-760X</orcidid></addata></record>
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ispartof Journal of chemical technology and biotechnology (1986), 2018-06, Vol.93 (6), p.1767-1777
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source Wiley-Blackwell Read & Publish Collection
subjects Atomic force microscopy
Cellulose
Cellulosic resins
Contact angle
Hydrometallurgy
Image contrast
Ionic liquids
Ions
Iron
iron(III)
Mechanical properties
membrane ageing
Membranes
Metal concentrations
Metal ions
Microscopy
Nanoindentation
Phase contrast
polymer inclusion membrane (PIM)
Polymers
Powder injection molding
Scanning electron microscopy
Separation
Zinc
zinc(II)
title Characterization of polymer inclusion membranes (PIM) containing phosphonium ionic liquids and their application for separation of Zn(II) from Fe(III)
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