Controlling the size of connecting windows in three-dimensionally ordered macroporous TiO2 for enhanced photocatalytic activity

Herein, for the first time, three-dimensionally ordered macroporous TiO 2 (3DOM-TiO 2 ) with well-tuned sizes of connecting windows were synthesized by regulation the driving force of the self-assembly process. 3DOM-TiO 2 materials exhibit a clear relationship between photocatalytic activities and c...

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Published in:Journal of materials science. Materials in electronics 2018-07, Vol.29 (14), p.11972-11981
Main Authors: Zhou, Man, Hou, Chujun, Chen, Jingwen, Jin, Jie, Ju, Lijun, Xu, Song, Yao, Chao, Li, Zhongyu
Format: Article
Language:English
Subjects:
Catalytic activity
Characterization and Evaluation of Materials
Chemistry and Materials Science
Materials Science
Optical and Electronic Materials
Photocatalysis
Self-assembly
Size effects
Stability
Titanium dioxide
Windows (intervals)
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container_end_page 11981
container_issue 14
container_start_page 11972
container_title Journal of materials science. Materials in electronics
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creator Zhou, Man
Hou, Chujun
Chen, Jingwen
Jin, Jie
Ju, Lijun
Xu, Song
Yao, Chao
Li, Zhongyu
description Herein, for the first time, three-dimensionally ordered macroporous TiO 2 (3DOM-TiO 2 ) with well-tuned sizes of connecting windows were synthesized by regulation the driving force of the self-assembly process. 3DOM-TiO 2 materials exhibit a clear relationship between photocatalytic activities and connecting window sizes, which provides a new perspective on the connecting window size effect. The possible mechanism of 3DOM-TiO 2 with window-size dependent effect is also proposed, and it would guide further design and synthesis of highly efficient photocatalysts with controllable inverse opal structures.
doi_str_mv 10.1007/s10854-018-9299-2
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subjects Catalytic activity
Characterization and Evaluation of Materials
Chemistry and Materials Science
Materials Science
Optical and Electronic Materials
Photocatalysis
Self-assembly
Size effects
Stability
Titanium dioxide
Windows (intervals)
title Controlling the size of connecting windows in three-dimensionally ordered macroporous TiO2 for enhanced photocatalytic activity
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