Electrochemical mechanism of Li insertion/extraction in ZnS and ZnS/C anodes for Li-ion batteries

• Published in: Electrochimica acta 2018-03, Vol.265, p.107-114
• Main Authors: Park, Ah-Ram, Jeon, Ki-Joon, Park, Cheol-Min
• Format: Article
• Language: English
• Subjects: Anode material; Anodes; Batteries; Chemical synthesis; Electrode materials; Electrodes; Fine structure; Lithium; Lithium-ion batteries; Lithium-ion battery; Nanocomposites; Reaction mechanism; Reaction mechanisms; Rechargeable batteries; Studies; X-ray diffraction; Zinc sulfide; Zn-based anode
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2018.01.158

Herein, we describe a simple solid-state synthesis of zinc sulfide (ZnS) and its amorphous carbon–modified nanocomposite (ZnS/C) and examine their performance as high-capacity anode materials for rechargeable Li-ion batteries, probing lithiation/delithiation mechanisms by ex situ X-ray diffraction and extended X-ray absorption fine structure analyses. The ZnS converted into LiZn and Li2S during lithiation, being subsequently incompletely recombined into ZnS during delithiation and thus resulting in traces of Zn and S. Based on the above investigation of reaction mechanism, the ZnS/C electrode was electrochemically tested within a potential range of 0–2.0 V vs. Li+/Li and exhibited a high reversible capacity of 681 mAh g−1, excellent cycling stability (>150 cycles), and high rate capability. [Display omitted] •ZnS and its nanocomposite were prepared using a straightforward high-energy ball milling.•The lithiation/delithiation mechanism was examined using ex situ XRD and EXAFS analyses.•The conversion during lithiation and recombination during delithiation was demonstrated.•ZnS/C electrode showed excellent electrochemical performances.