Electrochemical synthesis of thin, dense, and conformal anion exchange membranes with quaternary ammonium groups

We report for the first time the electrochemical synthesis in anodic and cathodic conditions of anion-conducting ionomer separators using two different precursors: N-(p-vinylbenzyl) N,N,N-trimethylammonium chloride (VBTMA) and (N-allyl N-benzyl N,N-dimethyl)ammonium iodide (ABDMA). The ionomer struc...

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Bibliographic Details
Published in:Electrochimica acta 2018-03, Vol.265, p.78-88
Main Authors: Braglia, M., Ferrari, I.V., Pasquini, L., Djenizian, T., Sette, M., Di Vona, M.L., Knauth, P.
Format: Article
Language:English
Subjects:
Alkaline fuel cells
Ammonia
Anion conductivity
Anion exchanging
Chain mobility
Chains
Chemical synthesis
Electrodeposition
Electrolytic cells
Fourier transforms
Ionomers
Membranes
Microstructure
NMR
Nuclear magnetic resonance
Scanning electron microscopy
Separators
Steric hindrance
Studies
Thin films
Water electrolysers
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Summary:We report for the first time the electrochemical synthesis in anodic and cathodic conditions of anion-conducting ionomer separators using two different precursors: N-(p-vinylbenzyl) N,N,N-trimethylammonium chloride (VBTMA) and (N-allyl N-benzyl N,N-dimethyl)ammonium iodide (ABDMA). The ionomer structure and microstructure are investigated by NMR and FTIR spectroscopies and Scanning Electron Microscopy. The quaternary ammonium groups are grafted in side chains (VBTMA) or are near the main chain (ABDMA). The anion conductivity is in the order of 1 mS/cm with quaternary ammonium groups in side chains and lower when the ammonium groups are near the main chain, where they probably reduce the anion mobility by steric hindrance. Such thin-film anion exchange membranes are a valuable asset for the realization of microfuel cells and solid-state water electrolysers. •Anion exchange membranes prepared by electrochemical synthesis.•Cathodic and anodic deposition conditions are explored.•Grafting of quaternary ammonium groups on side chains improves conductivity.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2018.01.151