Effects of low-pressure nitrogen plasma treatment on the surface properties and electrochemical performance of the polyethylene separator used lithium-ion batteries

• Published in: Japanese Journal of Applied Physics 2018-01, Vol.57 (1S), p.1
• Main Authors: Li, Chun, Li, Hsiao-Ling, Li, Chi-Heng, Liu, Yu-Shuan, Sung, Yu-Ching, Huang, Chun
• Format: Article
• Language: English
• Subjects: Contact angle; Contact pressure; Discharge; Electrochemical analysis; Fourier transforms; Free energy; Lithium; Lithium-ion batteries; Nitrogen; Nitrogen plasma; Polyethylene; Polyethylenes; Pressure effects; Rechargeable batteries; Scanning electron microscopy; Spectrum analysis; Surface properties; Wettability
• ISSN: 0021-4922; 1347-4065
• DOI: 10.7567/JJAP.57.01AB03

In this paper, we describe the surface transition of the polyethylene (PE) separator used in lithium-ion batteries treated by low-pressure nitrogen plasma discharge. The nitrogen-plasma-treated PE separator was characterized by contact angle measurement, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. The electrochemical performance of the lithium ion batteries fabricated with the nitrogen-plasma-treated separator was also evaluated. Results showed that polar functionalization groups were induced on the PE surface by the nitrogen plasma discharge, causing the surface to become hydrophilic. The increases in surface wettability and surface free energy result in electrolyte retention improvement. Moreover, the nitrogen plasma-treated PE separator leads to superior performance in lithium-ion battery assembly.