Catalyst Screening and Development for HI Decomposition in Sulfur-iodine Thermochemical Cycle for Hydrogen Production

The intrinsic activities of six important transition metals for HI decomposition were identified by kinetic study. Ru showed high activity and a low apparent activation barrier, indicating a good activity at low temperature. Ru/AC (Ru clusters supported on activated carbon) was designed and proved t...

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Published in:Chemistry letters 2018-06, Vol.47 (6), p.700-703
Main Authors: Fu, Guangshi, Wang, Zhihua, Wang, Lijian, He, Yong, Zhang, Yanwei, Cen, Kefa
Format: Article
Language:English
Subjects:
Activated carbon
Catalysis
Catalysts
Decomposition
Hydrogen production
Iodine
Ruthenium
Sulfur
Transition metals
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creator Fu, Guangshi
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description The intrinsic activities of six important transition metals for HI decomposition were identified by kinetic study. Ru showed high activity and a low apparent activation barrier, indicating a good activity at low temperature. Ru/AC (Ru clusters supported on activated carbon) was designed and proved to be a highly active, cost-effective, and long-term durable catalyst for HI decomposition. The present work could contribute to catalyst development for the industrialization of the sulfur-iodine thermochemical cycle for hydrogen production.
doi_str_mv 10.1246/cl.180131
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source Oxford Journals Online
subjects Activated carbon
Catalysis
Catalysts
Decomposition
Hydrogen production
Iodine
Ruthenium
Sulfur
Transition metals
title Catalyst Screening and Development for HI Decomposition in Sulfur-iodine Thermochemical Cycle for Hydrogen Production
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