Design of Postmetallocene Catalytic Systems of Arylimine Type for Olefin Polymerization: XVIII. Synthesis of N-Arylsalicylaldimine Ligands Containing meta-or para-Diallylamino Group and Their Titanium(IV) Complexes

Salicylaldehydes containing a tert -butyl or 2-phenylpropan-2-yl group in the 3-position reacted with N , N -diallyl- p -and - m -phenylenediamines in methanol to give the corresponding Schiff bases which were used as ligands to obtain titanium(IV) complexes with the composition L 2 TiCl 2 by reacti...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2018-04, Vol.54 (4), p.537-544
Main Authors: Oleynik, I. V., Oleynik, I. I.
Format: Article
Language:English
Subjects:
Catalysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Dichlorides
Imines
Ligands
Organic Chemistry
Review
Titanium
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Summary:Salicylaldehydes containing a tert -butyl or 2-phenylpropan-2-yl group in the 3-position reacted with N , N -diallyl- p -and - m -phenylenediamines in methanol to give the corresponding Schiff bases which were used as ligands to obtain titanium(IV) complexes with the composition L 2 TiCl 2 by reaction with diisopropoxytitanium dichloride.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428018040048