Loading…
Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation
This study reports the synthesis of ultrafine NiFe‐layered double hydroxide (NiFe‐LDH) nanosheets, possessing a size range between 1.5 and 3.0 nm with a thickness of 0.6 nm. Abundant metal and oxygen vacancies impart the ultrafine nanosheets with semi‐metallic character, and thus superior charge tra...
Saved in:
Published in: | Advanced energy materials 2018-06, Vol.8 (18), p.n/a |
---|---|
Main Authors: | , , , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3 |
---|---|
cites | cdi_FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3 |
container_end_page | n/a |
container_issue | 18 |
container_start_page | |
container_title | Advanced energy materials |
container_volume | 8 |
creator | Zhao, Yufei Zhang, Xin Jia, Xiaodan Waterhouse, Geoffrey I. N. Shi, Run Zhang, Xuerui Zhan, Fei Tao, Ye Wu, Li‐Zhu Tung, Chen‐Ho O'Hare, Dermot Zhang, Tierui |
description | This study reports the synthesis of ultrafine NiFe‐layered double hydroxide (NiFe‐LDH) nanosheets, possessing a size range between 1.5 and 3.0 nm with a thickness of 0.6 nm. Abundant metal and oxygen vacancies impart the ultrafine nanosheets with semi‐metallic character, and thus superior charge transfer properties and electrochemical water oxidation performance with overpotentials (η) of 254 mV relative to monolayer LDH nanosheets (η of 280 mV) or bulk LDH materials (η of 320 mV) at 10 mA cm−2. These results are highly encouraging for the future application of ultrafine monolayer LDH nanosheets in electronics, solar cells, and catalysis.
Ultrafine monolayer layered double hydroxide (LDH) nanosheets with a mean lateral size of less than 3 nm are obtained by the ultrasonic treatment of monolayer LDH nanosheets. Abundant vacancies impart the ultrafine nanosheets with semi‐metallic character, superior charge transfer properties, and electrocatalytic oxygen evolution performance relative to monolayer LDH nanosheets. |
doi_str_mv | 10.1002/aenm.201703585 |
format | article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2058556159</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2058556159</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3</originalsourceid><addsrcrecordid>eNqFkE1LAzEQhoMoWGqvngOetyb7kWaPpVYrtPWgxWPIxyzdsrupyS66N3-Cv9FfYkqlHp2BmYF53xl4ELqmZEwJiW8lNPU4JnRCkoxnZ2hAGU0jxlNyfpqT-BKNvN-REGlOSZIMUPHcqe_PrwQ3Nd5UrZNF2QBe2cZWsgeHl4cKBt_ZTlWAF71x9qM0gNeysX4L0HpcWIfnFejWWb2FutSywq-yDe6nIJVtaZsrdFHIysPotw_R5n7-MltEy6eHx9l0GemUkSyKlTI5N5CqOKRhKlPcpGySSF6AliTsmDGEMalynnOqOYd4opgGUzAGOhmim-PdvbNvHfhW7GznmvBSxCSAyRjN8qAaH1XaWe8dFGLvylq6XlAiDjjFAac44QyG_Gh4Lyvo_1GL6Xy9-vP-AGCoe-Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2058556159</pqid></control><display><type>article</type><title>Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation</title><source>Wiley</source><creator>Zhao, Yufei ; Zhang, Xin ; Jia, Xiaodan ; Waterhouse, Geoffrey I. N. ; Shi, Run ; Zhang, Xuerui ; Zhan, Fei ; Tao, Ye ; Wu, Li‐Zhu ; Tung, Chen‐Ho ; O'Hare, Dermot ; Zhang, Tierui</creator><creatorcontrib>Zhao, Yufei ; Zhang, Xin ; Jia, Xiaodan ; Waterhouse, Geoffrey I. N. ; Shi, Run ; Zhang, Xuerui ; Zhan, Fei ; Tao, Ye ; Wu, Li‐Zhu ; Tung, Chen‐Ho ; O'Hare, Dermot ; Zhang, Tierui</creatorcontrib><description>This study reports the synthesis of ultrafine NiFe‐layered double hydroxide (NiFe‐LDH) nanosheets, possessing a size range between 1.5 and 3.0 nm with a thickness of 0.6 nm. Abundant metal and oxygen vacancies impart the ultrafine nanosheets with semi‐metallic character, and thus superior charge transfer properties and electrochemical water oxidation performance with overpotentials (η) of 254 mV relative to monolayer LDH nanosheets (η of 280 mV) or bulk LDH materials (η of 320 mV) at 10 mA cm−2. These results are highly encouraging for the future application of ultrafine monolayer LDH nanosheets in electronics, solar cells, and catalysis.
Ultrafine monolayer layered double hydroxide (LDH) nanosheets with a mean lateral size of less than 3 nm are obtained by the ultrasonic treatment of monolayer LDH nanosheets. Abundant vacancies impart the ultrafine nanosheets with semi‐metallic character, superior charge transfer properties, and electrocatalytic oxygen evolution performance relative to monolayer LDH nanosheets.</description><identifier>ISSN: 1614-6832</identifier><identifier>EISSN: 1614-6840</identifier><identifier>DOI: 10.1002/aenm.201703585</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Catalysis ; Charge transfer ; defects ; Hydroxides ; Intermetallic compounds ; Iron compounds ; layered double hydroxide ; monolayer nanosheets ; Monolayers ; Nanosheets ; Nickel compounds ; Oxidation ; Photovoltaic cells ; Solar cells ; water oxidation</subject><ispartof>Advanced energy materials, 2018-06, Vol.8 (18), p.n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3</citedby><cites>FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3</cites><orcidid>0000-0002-7948-9413</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhao, Yufei</creatorcontrib><creatorcontrib>Zhang, Xin</creatorcontrib><creatorcontrib>Jia, Xiaodan</creatorcontrib><creatorcontrib>Waterhouse, Geoffrey I. N.</creatorcontrib><creatorcontrib>Shi, Run</creatorcontrib><creatorcontrib>Zhang, Xuerui</creatorcontrib><creatorcontrib>Zhan, Fei</creatorcontrib><creatorcontrib>Tao, Ye</creatorcontrib><creatorcontrib>Wu, Li‐Zhu</creatorcontrib><creatorcontrib>Tung, Chen‐Ho</creatorcontrib><creatorcontrib>O'Hare, Dermot</creatorcontrib><creatorcontrib>Zhang, Tierui</creatorcontrib><title>Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation</title><title>Advanced energy materials</title><description>This study reports the synthesis of ultrafine NiFe‐layered double hydroxide (NiFe‐LDH) nanosheets, possessing a size range between 1.5 and 3.0 nm with a thickness of 0.6 nm. Abundant metal and oxygen vacancies impart the ultrafine nanosheets with semi‐metallic character, and thus superior charge transfer properties and electrochemical water oxidation performance with overpotentials (η) of 254 mV relative to monolayer LDH nanosheets (η of 280 mV) or bulk LDH materials (η of 320 mV) at 10 mA cm−2. These results are highly encouraging for the future application of ultrafine monolayer LDH nanosheets in electronics, solar cells, and catalysis.
Ultrafine monolayer layered double hydroxide (LDH) nanosheets with a mean lateral size of less than 3 nm are obtained by the ultrasonic treatment of monolayer LDH nanosheets. Abundant vacancies impart the ultrafine nanosheets with semi‐metallic character, superior charge transfer properties, and electrocatalytic oxygen evolution performance relative to monolayer LDH nanosheets.</description><subject>Catalysis</subject><subject>Charge transfer</subject><subject>defects</subject><subject>Hydroxides</subject><subject>Intermetallic compounds</subject><subject>Iron compounds</subject><subject>layered double hydroxide</subject><subject>monolayer nanosheets</subject><subject>Monolayers</subject><subject>Nanosheets</subject><subject>Nickel compounds</subject><subject>Oxidation</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>water oxidation</subject><issn>1614-6832</issn><issn>1614-6840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQhoMoWGqvngOetyb7kWaPpVYrtPWgxWPIxyzdsrupyS66N3-Cv9FfYkqlHp2BmYF53xl4ELqmZEwJiW8lNPU4JnRCkoxnZ2hAGU0jxlNyfpqT-BKNvN-REGlOSZIMUPHcqe_PrwQ3Nd5UrZNF2QBe2cZWsgeHl4cKBt_ZTlWAF71x9qM0gNeysX4L0HpcWIfnFejWWb2FutSywq-yDe6nIJVtaZsrdFHIysPotw_R5n7-MltEy6eHx9l0GemUkSyKlTI5N5CqOKRhKlPcpGySSF6AliTsmDGEMalynnOqOYd4opgGUzAGOhmim-PdvbNvHfhW7GznmvBSxCSAyRjN8qAaH1XaWe8dFGLvylq6XlAiDjjFAac44QyG_Gh4Lyvo_1GL6Xy9-vP-AGCoe-Q</recordid><startdate>20180625</startdate><enddate>20180625</enddate><creator>Zhao, Yufei</creator><creator>Zhang, Xin</creator><creator>Jia, Xiaodan</creator><creator>Waterhouse, Geoffrey I. N.</creator><creator>Shi, Run</creator><creator>Zhang, Xuerui</creator><creator>Zhan, Fei</creator><creator>Tao, Ye</creator><creator>Wu, Li‐Zhu</creator><creator>Tung, Chen‐Ho</creator><creator>O'Hare, Dermot</creator><creator>Zhang, Tierui</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7948-9413</orcidid></search><sort><creationdate>20180625</creationdate><title>Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation</title><author>Zhao, Yufei ; Zhang, Xin ; Jia, Xiaodan ; Waterhouse, Geoffrey I. N. ; Shi, Run ; Zhang, Xuerui ; Zhan, Fei ; Tao, Ye ; Wu, Li‐Zhu ; Tung, Chen‐Ho ; O'Hare, Dermot ; Zhang, Tierui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Catalysis</topic><topic>Charge transfer</topic><topic>defects</topic><topic>Hydroxides</topic><topic>Intermetallic compounds</topic><topic>Iron compounds</topic><topic>layered double hydroxide</topic><topic>monolayer nanosheets</topic><topic>Monolayers</topic><topic>Nanosheets</topic><topic>Nickel compounds</topic><topic>Oxidation</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><topic>water oxidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Yufei</creatorcontrib><creatorcontrib>Zhang, Xin</creatorcontrib><creatorcontrib>Jia, Xiaodan</creatorcontrib><creatorcontrib>Waterhouse, Geoffrey I. N.</creatorcontrib><creatorcontrib>Shi, Run</creatorcontrib><creatorcontrib>Zhang, Xuerui</creatorcontrib><creatorcontrib>Zhan, Fei</creatorcontrib><creatorcontrib>Tao, Ye</creatorcontrib><creatorcontrib>Wu, Li‐Zhu</creatorcontrib><creatorcontrib>Tung, Chen‐Ho</creatorcontrib><creatorcontrib>O'Hare, Dermot</creatorcontrib><creatorcontrib>Zhang, Tierui</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced energy materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Yufei</au><au>Zhang, Xin</au><au>Jia, Xiaodan</au><au>Waterhouse, Geoffrey I. N.</au><au>Shi, Run</au><au>Zhang, Xuerui</au><au>Zhan, Fei</au><au>Tao, Ye</au><au>Wu, Li‐Zhu</au><au>Tung, Chen‐Ho</au><au>O'Hare, Dermot</au><au>Zhang, Tierui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation</atitle><jtitle>Advanced energy materials</jtitle><date>2018-06-25</date><risdate>2018</risdate><volume>8</volume><issue>18</issue><epage>n/a</epage><issn>1614-6832</issn><eissn>1614-6840</eissn><abstract>This study reports the synthesis of ultrafine NiFe‐layered double hydroxide (NiFe‐LDH) nanosheets, possessing a size range between 1.5 and 3.0 nm with a thickness of 0.6 nm. Abundant metal and oxygen vacancies impart the ultrafine nanosheets with semi‐metallic character, and thus superior charge transfer properties and electrochemical water oxidation performance with overpotentials (η) of 254 mV relative to monolayer LDH nanosheets (η of 280 mV) or bulk LDH materials (η of 320 mV) at 10 mA cm−2. These results are highly encouraging for the future application of ultrafine monolayer LDH nanosheets in electronics, solar cells, and catalysis.
Ultrafine monolayer layered double hydroxide (LDH) nanosheets with a mean lateral size of less than 3 nm are obtained by the ultrasonic treatment of monolayer LDH nanosheets. Abundant vacancies impart the ultrafine nanosheets with semi‐metallic character, superior charge transfer properties, and electrocatalytic oxygen evolution performance relative to monolayer LDH nanosheets.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aenm.201703585</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-7948-9413</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1614-6832 |
ispartof | Advanced energy materials, 2018-06, Vol.8 (18), p.n/a |
issn | 1614-6832 1614-6840 |
language | eng |
recordid | cdi_proquest_journals_2058556159 |
source | Wiley |
subjects | Catalysis Charge transfer defects Hydroxides Intermetallic compounds Iron compounds layered double hydroxide monolayer nanosheets Monolayers Nanosheets Nickel compounds Oxidation Photovoltaic cells Solar cells water oxidation |
title | Sub‐3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T19%3A20%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Sub%E2%80%903%20nm%20Ultrafine%20Monolayer%20Layered%20Double%20Hydroxide%20Nanosheets%20for%20Electrochemical%20Water%20Oxidation&rft.jtitle=Advanced%20energy%20materials&rft.au=Zhao,%20Yufei&rft.date=2018-06-25&rft.volume=8&rft.issue=18&rft.epage=n/a&rft.issn=1614-6832&rft.eissn=1614-6840&rft_id=info:doi/10.1002/aenm.201703585&rft_dat=%3Cproquest_cross%3E2058556159%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4605-2bbd98de4b2b2bd6b5b8d4673a8feca098d6dd066ab98981c88e27b6cedf66ec3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2058556159&rft_id=info:pmid/&rfr_iscdi=true |