Bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O2 under metal- and base-free conditions

We describe an eco-friendly, practical and operationally simple procedure for the bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with atmospheric dioxygen as the sole oxidant. This chemical process is clean with high conversion an...

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2018-01, Vol.20 (13), p.3038-3043
Main Authors: Kai-Jian, Liu, Jiang, Si, Ling-Hui, Lu, Ling-Li, Tang, Shan-Shan Tang, Hai-Shan Tang, Tang, Zilong, Wei-Min, He, Xu, Xinhua
Format: Article
Language:English
Subjects:
Alcohol
Alcohols
Carboxylic acids
Functional groups
Green chemistry
Ketones
Organic chemistry
Oxidation
Raw materials
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Summary:We describe an eco-friendly, practical and operationally simple procedure for the bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with atmospheric dioxygen as the sole oxidant. This chemical process is clean with high conversion and good selectivity, and an external initiator, catalyst, additive and base are not required. The virtue of this reaction is highlighted by its easily available and economical raw materials and excellent functional group tolerance (acid-, base- and oxidant-labile groups).
ISSN:1463-9262
1463-9270
DOI:10.1039/c8gc00223a