Understanding mechanisms of solid-state phase transformations by probing nuclear materials

• Published in: Journal of nuclear materials 2018-04, Vol.501, p.143-161
• Main Authors: Banerjee, Srikumar, Donthula, Harish
• Format: Article
• Language: English
• Subjects: Alloy systems; Alloys; Martensite; Martensitic stainless steel; Molybdenum; Nickel base alloys; Nuclear engineering; Omega phase; Order-disorder; Order-disorder transformations; Organic chemistry; Phase transformations; Phase transitions; Radiation; Radiation damage; Zirconium; Zirconium alloys; Zirconium base alloys
• ISSN: 0022-3115; 1873-4820
• DOI: 10.1016/j.jnucmat.2017.11.024

In this review a few examples will be cited to illustrate that a study on a specific nuclear material sometimes lead to a better understanding of scientific phenomena of broader interests. Zirconium alloys offer some unique opportunities in addressing fundamental issues such as (i) distinctive features between displacive and diffusional transformations, (ii) characteristics of shuffle and shear dominated displacive transformations and (iii) nature of mixed-mode transformations. Whether a transformation is of first or higher order?” is often raised while classifying it. There are rare examples, such as Ni-Mo alloys, in which during early stages of ordering the system experiences tendencies for both first order and second order transitions. Studies on the order-disorder transitions under a radiation environment have established the pathway for the evolution of ordering. These studies have also identified the temperature range over which the chemically ordered state remains stable in steady state under radiation.