Sensitive determination of hardness and fluoride in ground water by a hybrid nanosensor based on aggregation induced FRET on and off mechanism

• Published in: Sensors and actuators. B, Chemical Chemical, 2018-06, Vol.262, p.522-530
• Main Authors: Tian, Xike, Wang, Jiahuan, Li, Yong, Yang, Chao, Lu, Liqiang, Nie, Yulun
• Format: Article
• Language: English
• Subjects: Agglomeration; Calcium fluoride; Calcium ions; Energy transfer; Filter paper; Fluorescence; Fluoride detection; Gold; Groundwater; Hardness detection; Hybrid nanosensor; Nanoparticles; Nanosensors; Paper-based analytical device; Precipitation; Studies; Visual sensing; Water hardness; Water purification
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2018.02.020

[Display omitted] A novel hybrid nanosensor from carbon dots and hexametaphosphate capped Au NPs was applied for hardness and fluoride detection with high sensitivity, selectivity and visual ability based on aggregation induced FRET on and off mechanisms. •The nanosensor was fabricated by hybridizing CDs and capped Au NPs.•The nanosensor can be used for hardness determination with high sensitivity.•The nanosensor can detect fluoride in water with a detection limit of 0.339 ppm.•A paper sensor was fabricated for the visual detection of fluoride in water. Sensitive detection and determination of hardness and fluoride in the ground water is an important issue for the water safety. The present work reports a sensitive, selective, rapid and visual hybrid fluorescent nanosensor by hybridizing carbon dots and hexametaphosphate capped gold nanoparticles through intrinsic interactions of the two components. The hybrid nanosensor can be used for hardness (Ca2+, Mg2+) detection with the fluorescence intensity decreasing at 439 nm and increasing at 608 nm via the aggregation induced fluorescence resonance energy transfer on mechanism. In addition, the hybrid nanosensor mixed with calcium ions can detect fluoride in water with a lower detection limit of 0.339 ppm with the fluorescence color recovery based on the precipitation induced fluorescence resonance energy transfer off process. Experimental results indicate that the as-synthesized hybrid nanosensor has shown efficient feasibility and practicality for hardness and fluoride detection in actual groundwater samples. Furthermore, a paper-based analytical device has been fabricated by immobilizing the hybrid nanosensor on the cellulose filter paper for the visual and on-site detection of fluoride in water. The hybrid nanosensor would provide new sensing materials and mechanisms for the determination and detection of hardness and fluoride in the groundwater.