Metal-ion-mediated hydrogels with thermo-responsiveness for smart windows

• Published in: European polymer journal 2018-02, Vol.99, p.65-71
• Main Authors: Xin, Feifei, Lu, Qingliang, Liu, Bingxin, Yuan, Shichao, Zhang, Ruling, Wu, Yumin, Yu, Yueqin
• Format: Article
• Language: English
• Subjects: Acrylamide; Aluminum; Crosslinking; Dependence; Energy consumption; Free radical polymerization; Free radicals; Hydrogel; Hydrogels; Isopropylacrylamide; Metal ions; Methylene bisacrylamide; Polymerization; Smart window; Thermoresponsive; Tunable transparency
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2017.12.008

The transparency of poly(N-isopropylacrylamide-co-N-maleylgelatin) hydrogel could be tuned by temperature and concentration of Al3+. The doulb-network hydrogel could be formed with the addition of 0.5 M Al3+. [Display omitted] •The composite hydrogel is composed of P(N-isopropylacrylamide) and natural biopolymer gelatin.•The hydrogel is responsive to temperature and metal ions.•The transparency of the hydrogel could be facilely tuned by temperature and concentration of Al3+.•0.5 M Al3+ could induce the formation of double-network hydrogel. The poly(N-isopropylacrylamide-co-N-maleylgelatin) [P(NIPAAm-co-N-MAGEL)] hydrogel was prepared by the free radical polymerization of N-isopropylacrylamide (NIPAAm) and N-maleylgelatin (N-MAGEL) with N,N′-methylene bis(acrylamide) (BIS) as the cross linker in the complete aqueous environment. The hydrogel becomes opaque when the temperature exceeds lower critical solution temperature (LCST) and goes back to its original transparent state when it is cooled below the LCST which can be finely tuned as it shows a linear dependence on the concentration of Na+, Mg2+ and Al3+. Interestingly, different from Na+ and Mg2+, Al3+ could mediate the transparency of the hydrogel even when the temperature is below LCST and induce the formation of double-network (DN) hydrogel. Metal-ion-carboxylate supramolecular interactions are proposed to dominate this property through ionic cross-linking. The hydrogel could be used as the temperature and metal ions controlled smart window. Effects of metal ions on swelling characteristics, mechanical property and microstructures of the hydrogel were further investigated.