Synthesis of modified sepiolite-g-polystyrene sulfonic acid nanohybrids by radiation induced graft polymerization

In this study, polystyrene (PS) grafted sepiolite nanohybrid (MS-g-PS) was synthesized by using simultaneous radiation grafting technique in the presence of dichloromethane (DCM) as solvent. The radiation grafting process was carried out under inert atmosphere at room temperature using gamma rays fr...

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Bibliographic Details
Published in:Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2018-07, Vol.148, p.19-24
Main Authors: Taimur, Shaista, Hassan, Muhammad Inaam ul, Yasin, Tariq, Ali, Syed Wasim
Format: Article
Language:English
Subjects:
Acids
Chemical synthesis
Dichloromethane
Diffraction
Emission analysis
Field emission microscopy
Fourier transforms
Gamma rays
Grafting
Gravimetry
Inert atmospheres
Infrared spectroscopy
Ion exchange resins
Nanohybrid
Polymerization
Polystyrene resins
Radiation
Radiation effects
Radiation grafting
Scanning electron microscopy
Sepiolite
Styrene
Styrenes
Sulfonic acid
Sulfuric acid
X-ray diffraction
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Summary:In this study, polystyrene (PS) grafted sepiolite nanohybrid (MS-g-PS) was synthesized by using simultaneous radiation grafting technique in the presence of dichloromethane (DCM) as solvent. The radiation grafting process was carried out under inert atmosphere at room temperature using gamma rays from a Co-60 irradiator. The degree of grafting was affected by absorbed dose and monomer concentration in the mixture. Sulfonation of synthesized nanohybrid was carried out with sulfuric acid. Both the grafting of styrene and its sulfonate derivative were verified by Fourier transform infrared spectroscopy (FT-IR). The structural and morphological investigations of these nanohybrids have been investigated by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The gravimetric investigations showed that grafting yield increases with the absorbed dose. Results showed that the system allows the controlled grafting of styrene onto sepiolite (Sep) in DCM. •Synthesis of nanohybrid adsorbent material using simultaneous radiation grafting technique.•Grafting yield of polystyrene onto sepiolite was 177% at dose of 70 kGy.•The sulfonation of grafted nanohybrids has been carried out by using sulfuric acid.•The developed adsorbent is cost effective and can be used for metal recovery.
ISSN:0969-806X
1879-0895
DOI:10.1016/j.radphyschem.2018.02.020