Lattice dynamics of ASb2O6 (A=Cu,Co) with trirutile structure

Raman spectroscopy experiments on single crystals of CuSb2O6 and CoSb2O6 quasi-one-dimensional antiferromagnets with trirutile crystal structure were performed, with a focus on the first material. The observed Raman-active phonon modes and previously reported infrared-active modes were identified wi...

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Bibliographic Details
Published in:arXiv.org 2018-01
Main Authors: Maimone, D T, Christian, A B, Neumeier, J J, Granado, E
Format: Article
Language:English
Subjects:
Antiferromagnetism
Crossovers
Crystal structure
Crystals
Elongation
Jahn-Teller effect
Lattice vibration
Monoclinic lattice
Order-disorder transformations
Phonons
Raman spectroscopy
Single crystals
Spectrum analysis
Symmetry
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Summary:Raman spectroscopy experiments on single crystals of CuSb2O6 and CoSb2O6 quasi-one-dimensional antiferromagnets with trirutile crystal structure were performed, with a focus on the first material. The observed Raman-active phonon modes and previously reported infrared-active modes were identified with the aid of ab-initio lattice dynamics calculations. The structural transition between monoclinic beta-CuSb2O6 and tetragonal alpha-CuSb2O6 phases at Ts=400 K is manifested in our spectra by a "repulsion" of two accidentally quasi-degenerate symmetric modes below Ts, caused by a phonon mixing effect that is only operative in the monoclinic beta-CuSb2O6 phase due to symmetry restrictions. Also, two specific phonons, associated with CuO6 octahedra rotation and with a Jahn-Teller elongation mode, soften and broaden appreciably as T -> Ts. A crossover from a displacive to an order-disorder transition at Ts is inferred.
ISSN:2331-8422
DOI:10.48550/arxiv.1801.10549