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Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8
In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO 3 ) 2 as Ni(II) source. The Ni/...
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Published in: | Journal of porous materials 2018, Vol.25 (5), p.1349-1358 |
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container_title | Journal of porous materials |
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creator | Yousofvand, Zakieh Hajjami, Maryam Ghorbani, Farshid Ghafouri-Nejad, Raziyeh |
description | In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO
3
)
2
as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N
2
sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability. |
doi_str_mv | 10.1007/s10934-017-0545-4 |
format | article |
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3
)
2
as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N
2
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3
)
2
as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N
2
sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.</description><subject>Aromatic compounds</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Halides</subject><subject>Infrared radiation</subject><subject>Physical Chemistry</subject><subject>Trimethoxysilylpropanethiol</subject><issn>1380-2224</issn><issn>1573-4854</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1UcmO1DAQjRBIDAMfwM0SF5AweEvKOQ4jlpZGcGg4W05sE4-CHew0EH6U36G6GwkunOzy28p6TfOYsxecMXhZOeuloowDZa1qqbrTXPAWJFW6VXfxLjWjQgh1v3lQ6y1jrNcAF82v_ZbWyddYSQ7kfXy62z2j8nlLXRynOZdMBZ02V_KPbfDpp0--HuaQ0zaTEx6dJ_WwLLms3pH9qyvKW2KTI3GtxC7LHEe7xpyIxZEkm3LxdlxzIfhu562uJOCAK5D67yYu2oIZxzCMqORbtOSkPHohfkInO5_A73Gd0CLmA1II2u31w-ZesHP1j_6cl82nN68_Xr-jNx_e7q6vbugoOq2oGgYOKoB1THUgBzZycNx3vdfagR4EH1kvgpZ9AD2CshKgb6WCAL61XScvmydn36XkrwdfV3OLWySMNIKBgE7yrkUWP7PGkmstPpilxC_4B8OZOfZnzv0Z7M8c-zMKNeKsqchNn3356_x_0W-TMKCB</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Yousofvand, Zakieh</creator><creator>Hajjami, Maryam</creator><creator>Ghorbani, Farshid</creator><creator>Ghafouri-Nejad, Raziyeh</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2018</creationdate><title>Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8</title><author>Yousofvand, Zakieh ; Hajjami, Maryam ; Ghorbani, Farshid ; Ghafouri-Nejad, Raziyeh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2684-4bb174f7ad04673b0c17d1e69e88d78b21c092f839f78c74a37795347f7e5a663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aromatic compounds</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Halides</topic><topic>Infrared radiation</topic><topic>Physical Chemistry</topic><topic>Trimethoxysilylpropanethiol</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yousofvand, Zakieh</creatorcontrib><creatorcontrib>Hajjami, Maryam</creatorcontrib><creatorcontrib>Ghorbani, Farshid</creatorcontrib><creatorcontrib>Ghafouri-Nejad, Raziyeh</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of porous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yousofvand, Zakieh</au><au>Hajjami, Maryam</au><au>Ghorbani, Farshid</au><au>Ghafouri-Nejad, Raziyeh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8</atitle><jtitle>Journal of porous materials</jtitle><stitle>J Porous Mater</stitle><date>2018</date><risdate>2018</risdate><volume>25</volume><issue>5</issue><spage>1349</spage><epage>1358</epage><pages>1349-1358</pages><issn>1380-2224</issn><eissn>1573-4854</eissn><abstract>In the present work, SBA-15 mesoporous grafted with 3-(trimethoxysilyl)-1-propanethiol as a linker and subsequently reacted by 3, 5-dichloro-2-hydroxybenzenesulfonyl chloride. Then to obtain the new catalyst Ni(II) was supported on functionalized SBA-15 by using Ni(NO
3
)
2
as Ni(II) source. The Ni/SBA-15 catalyst was characterized with SEM, EDS, ICP, XRD, TGA, FT-IR and N
2
sorption–desorption analysis. The key advantages of this heterogeneous catalyst are inexpensive, short reaction times, excellent yields, recovery and reusability.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10934-017-0545-4</doi><tpages>10</tpages></addata></record> |
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subjects | Aromatic compounds Catalysis Catalysts Characterization and Evaluation of Materials Chemical synthesis Chemistry Chemistry and Materials Science Halides Infrared radiation Physical Chemistry Trimethoxysilylpropanethiol |
title | Synthesis of Ni(II)-3,5-dichloro-2-hydroxybenzenesulfonyl chloride supported SBA-15 and its application as a nanoreactor catalyst for the synthesis of diaryl sulfides via reaction of aryl halides with thiourea or S8 |
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