Phase Composition, Structure, and Hydrolytic Stability of Sodium-Aluminum(Iron) Phosphate Glass Containing Rare-Earth Oxides

The phase composition, structure, elemental distribution, and hydrolytic stability of quench-hardened and tempered sodium-aluminum-phosphate (SAP) and sodium-aluminum(iron) phosphate (SAIP) glass materials containing 10 wt.% (above 100%) oxides of rare earth elements (REE) were studied. It is shown...

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Published in:Glass and ceramics 2018-07, Vol.75 (3-4), p.89-94
Main Authors: Stefanovskii, S. V., Stefanovskaya, O. I., Semenova, D. V., Kadyko, M. I., Danilov, S. S.
Format: Article
Language:English
Subjects:
Aluminum
Amorphous materials
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Crystallization
Glass
Hardening rate
Hostages
Iron
Leaching
Materials Science
Melts (crystal growth)
Natural Materials
Oxides
Phase composition
Phosphate glass
Phosphates
Rare earth compounds
Rare earth elements
Rare earth metals
Sodium
Structural stability
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cited_by cdi_FETCH-LOGICAL-c355t-ade3951a888ef0750d23b8e921620aaf7d2b22257ac2263fa0ec7a6cbd075b113
cites cdi_FETCH-LOGICAL-c355t-ade3951a888ef0750d23b8e921620aaf7d2b22257ac2263fa0ec7a6cbd075b113
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container_issue 3-4
container_start_page 89
container_title Glass and ceramics
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creator Stefanovskii, S. V.
Stefanovskaya, O. I.
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Danilov, S. S.
description The phase composition, structure, elemental distribution, and hydrolytic stability of quench-hardened and tempered sodium-aluminum-phosphate (SAP) and sodium-aluminum(iron) phosphate (SAIP) glass materials containing 10 wt.% (above 100%) oxides of rare earth elements (REE) were studied. It is shown that all materials obtained by quench-hardening melts (except La-containing melts) were x-ray amorphous, while slowly cooled (tempered) melts partially or completely crystallized with different phases of orthophosphates being released. The rate of leaching of elements from tempered SAP glasses determined at 90°C is approximately one or two orders of magnitude higher than then for the quench-hardened glasses, and the leach rate of elements from quench-hardened SAIP glasses is lower than from quench-hardened SAP glasses.
doi_str_mv 10.1007/s10717-018-0034-5
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source EBSCOhost Art & Architecture Source; Springer Link
subjects Aluminum
Amorphous materials
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Crystallization
Glass
Hardening rate
Hostages
Iron
Leaching
Materials Science
Melts (crystal growth)
Natural Materials
Oxides
Phase composition
Phosphate glass
Phosphates
Rare earth compounds
Rare earth elements
Rare earth metals
Sodium
Structural stability
title Phase Composition, Structure, and Hydrolytic Stability of Sodium-Aluminum(Iron) Phosphate Glass Containing Rare-Earth Oxides
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