Nanosize effect: Enhanced compensation temperature and existence of magneto-dielectric coupling in SmFeO3

In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas, including therapeutics, imaging, electronic devices, communic...

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Bibliographic Details
Published in:arXiv.org 2017-06
Main Authors: Chaturvedi, Smita, Priyank Shyam, Bag, Rabindranath, Shirolkar, Mandar M, Kumar, Jitender, Kaur, Harleen, Singh, Surjeet, Awasthi, A M, Kulkarni, Sulabha
Format: Article
Language:English
Subjects:
Antiferromagnetism
Catalysis
Chemical properties
Compensation
Dielectric properties
Dielectric strength
Electronic devices
Ferroelectric materials
Ferroelectricity
Ferromagnetism
Magnetic permeability
Magnetic properties
Nanoparticles
Organic chemistry
Quantum confinement
Single crystals
Thermodynamic properties
Transition metal oxides
Transition metals
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Summary:In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas, including therapeutics, imaging, electronic devices, communication systems, sensors, and catalysis. We have analyzed structural, magnetic, dielectric, and thermal properties of weakly ferromagnetic SmFeO3 nanoparticles of sizes about 55 nm and 500 nm. The nano-size particles exhibit several distinct features that are neither observed in their larger-size variants nor reported previously for the single crystals. In particular, for the 55 nm particle, we observe six-fold enhancement of compensation temperature, an unusual rise in susceptibility in the temperature range 550 to 630 K due to spin pinning, and coupled antiferromagnetic-ferroelectric transition, directly observed in the dielectric constant.
ISSN:2331-8422
DOI:10.48550/arxiv.1611.02850