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Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes
Crystallographic, emission and NMR studies of a series of C 3 -symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb( iii ) and Eu( iii ) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudoc...
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| Published in: | Chemical communications (Cambridge, England) England), 2018-07, Vol.54 (61), p.8486-8489 |
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| Main Authors: | , , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c373t-ee4f1b1d47371742329ba7d50e9b8881d766a6e884f9596abc869fa3579acc843 |
| container_end_page | 8489 |
| container_issue | 61 |
| container_start_page | 8486 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 54 |
| creator | Mason, Kevin Harnden, Alice C Patrick, Connor W Poh, Adeline W. J Batsanov, Andrei S Suturina, Elizaveta A Vonci, Michele McInnes, Eric J. L Chilton, Nicholas F Parker, David |
| description | Crystallographic, emission and NMR studies of a series of
C
3
-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(
iii
) and Eu(
iii
) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.
The second coordination sphere determines ligand field in lanthanide coordination complexes. |
| doi_str_mv | 10.1039/c8cc04995e |
| format | article |
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C
3
-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(
iii
) and Eu(
iii
) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.
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C
3
-symmetric, nine-coordinate substituted pyridyl triazacyclononane Yb(
iii
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iii
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C
3
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iii
) and Eu(
iii
) complexes reveal the impact of local solvation and ligand dipolar polarisability on ligand field strength, leading to dramatic variations in pseudocontact NMR shifts and emission spectral profiles, giving new guidance for responsive NMR and spectral probe design.
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018-07, Vol.54 (61), p.8486-8489 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_2076296482 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Crystallography Emission analysis Field strength Ligands NMR Nuclear magnetic resonance Solvation |
| title | Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes |
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