Influence of nitrogen-doping in carbon on equivalent distributed resistance and capacitance – Implications to electrocatalysis of oxygen reduction reaction

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2017-11, Vol.805, p.184-192
• Main Authors: Bera, Bapi, Kar, Tathagata, Chakraborty, Arup, Neergat, Manoj
• Format: Article
• Language: English
• Subjects: Ammonia; Analytical chemistry; Capacitance; Carbon; Catalysis; Catalysts; Electrocatalysis; Electrochemical impedance spectroscopy; Equivalence; Equivalent distributed resistance; Heat treatment; Melamine; Nitrogen; Nitrogen-doped carbon; Oxygen reduction reaction; Oxygen reduction reactions; Precursors; Reduced graphene oxide
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2017.10.025

Carbon-black is heat-treated with nitrogen-containing precursor (ammonia or melamine) to yield N-doped carbon. The nitrogen content in the sample depends on the type of the precursor and the heat-treatment temperature and it is estimated using CHN analysis. The electrochemical impedance spectroscopy (EIS) patterns of the samples recorded in argon-saturated 0.1M KOH show a high-frequency equivalent distributed resistance (EDR) and a low-frequency capacitive straight line, tilted slightly away from the y-axis. The EDR and the tilt of the capacitive straight line decrease with increase in nitrogen-content in the N-doped carbon samples. Further, EIS of oxygen reduction reaction (ORR) is recorded with carbon and N-doped carbon in oxygen-saturated 0.1M KOH. The EIS patterns of ORR suggest that the high-frequency EDR feature is not negligible, unlike that with carbon-supported and unsupported Pt catalysts in both acidic and alkaline media. Therefore, nitrogen content and EDR have important implications in deciding the electrocatalytic activity and the features of the EIS patterns of carbon-based metal-free catalysts. Because of the change in EDR and the capacitance with nitrogen-content, the EIS patterns of ORR with N-doped carbon are complex to analyze. •High-frequency equivalent distributed resistance (EDR) decreases and capacitance increases with nitrogen content in the carbon-based samples•The EDR feature cannot be neglected from the EC analysis of ORR•The decrease in EDR and the rise in capacitance make the analysis of the EIS of ORR on N-doped carbon more complex•The EDR value is negligible with metal containing catalysts