Role of reduced graphene oxide as nano-electrocatalyst in carbon felt electrode of vanadium redox flow battery

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2017-03, Vol.789, p.67-75
• Main Authors: Moghim, Mohammad Hadi, Eqra, Rahim, Babaiee, Mohsen, Zarei-Jelyani, Mohammad, Loghavi, Mohammad Mohsen
• Format: Article
• Language: English
• Subjects: Carbon; Carbon felt; Catalysts; Charge transfer; Chemical compounds; Diffusion coefficient; Electrocatalysis; Electrocatalysts; Electrochemical analysis; Electrodes; Electrolytes; Electron micrographs; Equivalent circuits; Graphene; Inks; Nanoparticles; Nyquist plots; Rechargeable batteries; Reduced graphene oxide; Vanadium; Vanadium redox flow battery
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2017.02.031

Carbon-based electrodes are usually used in vanadium redox flow batteries and electrochemical performance of these electrodes can be modified by electrocatalysts. In the current study, reduced graphene oxide inks with different concentrations were used to modify a carbon felt electrode. It was observed that CF which was modified in 2 mg/ml ink (CF-G-2) had the optimum combination of electrochemical properties, because no significant peak current improvement was observed at higher graphene contents and it also had the minimum value of ΔEp. The anodic and cathodic peak currents for positive redox couple reaction in CF-G-2 reached to 45.3 and 21.1 mA respectively, in comparison with 14.2 and 4.7 mA values for bare felt. Linear diffusion coefficient was also enhanced more than two times with the incorporation of graphene. Nyquist plots of CF-G in different electrolytes (VOSO4/V2O5 and VOSO4) showed different shapes and equivalent circuit data indicated much lower charge transfer resistance for modified carbon felts with graphene. The diffusion process was remarkably facilitated with the incorporation of reduced graphene oxide and graphene had desirable influence on the electrolyte absorption of carbon felt. Finally, scanning electron micrographs of electrodes demonstrated loaded graphene nanosheets on the surface of carbon felt fibers. [Display omitted] •Reduced graphene oxide used as nano-electrocatalyst of VRFB carbon felt electrode.•A practical impregnation method was used to deposit reduced graphene oxide.•Incorporation of graphene exhibited a significant increase in electrochemical activity.•Graphene increased carbon felt electrolyte absorption to more than 7.3 times.