Self-organizing structures in immiscible crystals

Spinodal decomposition process in the system of immiscible PbTe/CdTe compounds is analyzed as an example of a self-organizing structure. The immiscibility of the constituents leads to the observed morphological transformations like anisotropy driven formation of quantum dots and nanowires, and to th...

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Bibliographic Details
Published in:arXiv.org 2016-05
Main Authors: Mińkowski, Marcin, Załuska-Kotur, Magdalena A, Turski, Łukasz A, Karczewski, Grzegorz
Format: Article
Language:English
Subjects:
Anisotropy
Computer simulation
Crystal structure
Diffusion
Intermetallic compounds
Lead tellurides
Miscibility
Multilayers
Nanowires
Phase separation
Quantum dots
Spinodal decomposition
Surface diffusion
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Summary:Spinodal decomposition process in the system of immiscible PbTe/CdTe compounds is analyzed as an example of a self-organizing structure. The immiscibility of the constituents leads to the observed morphological transformations like anisotropy driven formation of quantum dots and nanowires, and to the phase separation at the highest temperatures. Proposed model accomplishes bulk and surface diffusion together with the anisotropic mobility of material components. We analyze its properties by kinetic Monte Carlo simulations and show that it is able to reproduce all of the structures observed experimentally in the process of PbTe/CdTe growth. We show that studied mechanisms of dynamic processes play different role in the creation of zero--, one--, two-- and finally three-dimensional structures. The shape of grown structures is different for relatively thick multilayers when bulk diffusion cooperates with the anisotropic mobility, in annealed structure when isotropic bulk diffusion only decides about the process and finally for thin multilayers when surface diffusion is the most decisive factor. We compare our results with experimentally grown systems and show that proposed model explains the diversity of observed structures.
ISSN:2331-8422