End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes

Kanonaite, with compositions plotting on the join Mn3+AlSiO5-Fe3+AlSiO5, was discovered in a late quartz vein of the Le Coreux metamorphic manganese deposit. A typical structural formula is (Mn3+3.69Fe3+0.36)Al3.95Si4.00O20, representing maximum solid solution within the system Al2SiO5-Mn2SiO5-Fe2Si...

Full description

Saved in:
Bibliographic Details
Published in:Contributions to mineralogy and petrology 2004-05, Vol.147 (3), p.276
Main Authors: Schreyer, Werner, Heinz-Jurgen Bernhardt, Andre-Mathier Fransolet
Format: Article
Language:English
Subjects:
Crystals
Kaolinite
Manganese
Metamorphism
Mineralogy
Minerals
Petrology
Quartz
Veins (geology)
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 3
container_start_page 276
container_title Contributions to mineralogy and petrology
container_volume 147
creator Schreyer, Werner
Heinz-Jurgen Bernhardt
Andre-Mathier Fransolet
description Kanonaite, with compositions plotting on the join Mn3+AlSiO5-Fe3+AlSiO5, was discovered in a late quartz vein of the Le Coreux metamorphic manganese deposit. A typical structural formula is (Mn3+3.69Fe3+0.36)Al3.95Si4.00O20, representing maximum solid solution within the system Al2SiO5-Mn2SiO5-Fe2SiO5. Refractive indices are =1.777; =1.855. The end-member compositions form the outermost, latest products in zoned crystals ranging to less manganiferous kanonaite. A crystal structure determination of a Mn-rich kanonaite confirms that about 96% of all the Mn3+ present is located in the strongly Jahn-Teller-distorted octahedron of the andalusite-type structure. Combining all relevant mineral-chemical and petrological data available on the deposit, a speculative model is presented in which kanonaite crystals with successively higher Mn3+ contents form during decreasing temperatures in the course of the anticlockwise PTt path of extensional metamorphism. Kaolinite occurring in zones within composite kanonaite porphyroblasts of adjacent phyllites is regarded here as by-product of a continuous retrograde breakdown reaction of less manganiferous kanonaite. In places, kanonaite was peripherally replaced by muscovite and Mn- and Fe-oxides. [PUBLICATION ABSTRACT]
doi_str_mv 10.1007/s00410-004-0557-3
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_208182488</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>781983171</sourcerecordid><originalsourceid>FETCH-proquest_journals_2081824883</originalsourceid><addsrcrecordid>eNqNi8tOwzAQRS0EEuHxAexGrEBgGOdBYnYVasWGHfvKJRMlxZmkfoCKxL_XCz6Azb06OvcKcaXwQSHWjx6xVChTSqyqWhZHIlNlkUvUT_WxyBCTrbXWp-LM-y0mbnSVid8lt3KkcUMOOnJuMAyfhic2Q6BnWDAYbo2NPiHMvfEE30PoYWKChYUuWrsHR7M1H9TCZg83b3wPK7ot7mBIZ9hF48IPfFGizk0jhD49XUvM5C_ESWesp8u_PhfXq-X7y6uc3bSL5MN6O0XHSa1zbFSTl01T_Gt0AON7U0w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>208182488</pqid></control><display><type>article</type><title>End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes</title><source>Springer Link</source><creator>Schreyer, Werner ; Heinz-Jurgen Bernhardt ; Andre-Mathier Fransolet</creator><creatorcontrib>Schreyer, Werner ; Heinz-Jurgen Bernhardt ; Andre-Mathier Fransolet</creatorcontrib><description>Kanonaite, with compositions plotting on the join Mn3+AlSiO5-Fe3+AlSiO5, was discovered in a late quartz vein of the Le Coreux metamorphic manganese deposit. A typical structural formula is (Mn3+3.69Fe3+0.36)Al3.95Si4.00O20, representing maximum solid solution within the system Al2SiO5-Mn2SiO5-Fe2SiO5. Refractive indices are =1.777; =1.855. The end-member compositions form the outermost, latest products in zoned crystals ranging to less manganiferous kanonaite. A crystal structure determination of a Mn-rich kanonaite confirms that about 96% of all the Mn3+ present is located in the strongly Jahn-Teller-distorted octahedron of the andalusite-type structure. Combining all relevant mineral-chemical and petrological data available on the deposit, a speculative model is presented in which kanonaite crystals with successively higher Mn3+ contents form during decreasing temperatures in the course of the anticlockwise PTt path of extensional metamorphism. Kaolinite occurring in zones within composite kanonaite porphyroblasts of adjacent phyllites is regarded here as by-product of a continuous retrograde breakdown reaction of less manganiferous kanonaite. In places, kanonaite was peripherally replaced by muscovite and Mn- and Fe-oxides. [PUBLICATION ABSTRACT]</description><identifier>ISSN: 0010-7999</identifier><identifier>EISSN: 1432-0967</identifier><identifier>DOI: 10.1007/s00410-004-0557-3</identifier><identifier>CODEN: CMPEAP</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Crystals ; Kaolinite ; Manganese ; Metamorphism ; Mineralogy ; Minerals ; Petrology ; Quartz ; Veins (geology)</subject><ispartof>Contributions to mineralogy and petrology, 2004-05, Vol.147 (3), p.276</ispartof><rights>Springer-Verlag 2004</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Schreyer, Werner</creatorcontrib><creatorcontrib>Heinz-Jurgen Bernhardt</creatorcontrib><creatorcontrib>Andre-Mathier Fransolet</creatorcontrib><title>End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes</title><title>Contributions to mineralogy and petrology</title><description>Kanonaite, with compositions plotting on the join Mn3+AlSiO5-Fe3+AlSiO5, was discovered in a late quartz vein of the Le Coreux metamorphic manganese deposit. A typical structural formula is (Mn3+3.69Fe3+0.36)Al3.95Si4.00O20, representing maximum solid solution within the system Al2SiO5-Mn2SiO5-Fe2SiO5. Refractive indices are =1.777; =1.855. The end-member compositions form the outermost, latest products in zoned crystals ranging to less manganiferous kanonaite. A crystal structure determination of a Mn-rich kanonaite confirms that about 96% of all the Mn3+ present is located in the strongly Jahn-Teller-distorted octahedron of the andalusite-type structure. Combining all relevant mineral-chemical and petrological data available on the deposit, a speculative model is presented in which kanonaite crystals with successively higher Mn3+ contents form during decreasing temperatures in the course of the anticlockwise PTt path of extensional metamorphism. Kaolinite occurring in zones within composite kanonaite porphyroblasts of adjacent phyllites is regarded here as by-product of a continuous retrograde breakdown reaction of less manganiferous kanonaite. In places, kanonaite was peripherally replaced by muscovite and Mn- and Fe-oxides. [PUBLICATION ABSTRACT]</description><subject>Crystals</subject><subject>Kaolinite</subject><subject>Manganese</subject><subject>Metamorphism</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Petrology</subject><subject>Quartz</subject><subject>Veins (geology)</subject><issn>0010-7999</issn><issn>1432-0967</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqNi8tOwzAQRS0EEuHxAexGrEBgGOdBYnYVasWGHfvKJRMlxZmkfoCKxL_XCz6Azb06OvcKcaXwQSHWjx6xVChTSqyqWhZHIlNlkUvUT_WxyBCTrbXWp-LM-y0mbnSVid8lt3KkcUMOOnJuMAyfhic2Q6BnWDAYbo2NPiHMvfEE30PoYWKChYUuWrsHR7M1H9TCZg83b3wPK7ot7mBIZ9hF48IPfFGizk0jhD49XUvM5C_ESWesp8u_PhfXq-X7y6uc3bSL5MN6O0XHSa1zbFSTl01T_Gt0AON7U0w</recordid><startdate>20040501</startdate><enddate>20040501</enddate><creator>Schreyer, Werner</creator><creator>Heinz-Jurgen Bernhardt</creator><creator>Andre-Mathier Fransolet</creator><general>Springer Nature B.V</general><scope>3V.</scope><scope>7TN</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>H96</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L.G</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>R05</scope></search><sort><creationdate>20040501</creationdate><title>End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes</title><author>Schreyer, Werner ; Heinz-Jurgen Bernhardt ; Andre-Mathier Fransolet</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_2081824883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Crystals</topic><topic>Kaolinite</topic><topic>Manganese</topic><topic>Metamorphism</topic><topic>Mineralogy</topic><topic>Minerals</topic><topic>Petrology</topic><topic>Quartz</topic><topic>Veins (geology)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schreyer, Werner</creatorcontrib><creatorcontrib>Heinz-Jurgen Bernhardt</creatorcontrib><creatorcontrib>Andre-Mathier Fransolet</creatorcontrib><collection>ProQuest Central (Corporate)</collection><collection>Oceanic Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Earth, Atmospheric &amp; Aquatic Science</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy &amp; Non-Living Resources</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Materials Science Database</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) Professional</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest research library</collection><collection>ProQuest Science Journals</collection><collection>ProQuest Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>ProQuest Earth, Atmospheric &amp; Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>University of Michigan</collection><jtitle>Contributions to mineralogy and petrology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schreyer, Werner</au><au>Heinz-Jurgen Bernhardt</au><au>Andre-Mathier Fransolet</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes</atitle><jtitle>Contributions to mineralogy and petrology</jtitle><date>2004-05-01</date><risdate>2004</risdate><volume>147</volume><issue>3</issue><spage>276</spage><pages>276-</pages><issn>0010-7999</issn><eissn>1432-0967</eissn><coden>CMPEAP</coden><abstract>Kanonaite, with compositions plotting on the join Mn3+AlSiO5-Fe3+AlSiO5, was discovered in a late quartz vein of the Le Coreux metamorphic manganese deposit. A typical structural formula is (Mn3+3.69Fe3+0.36)Al3.95Si4.00O20, representing maximum solid solution within the system Al2SiO5-Mn2SiO5-Fe2SiO5. Refractive indices are =1.777; =1.855. The end-member compositions form the outermost, latest products in zoned crystals ranging to less manganiferous kanonaite. A crystal structure determination of a Mn-rich kanonaite confirms that about 96% of all the Mn3+ present is located in the strongly Jahn-Teller-distorted octahedron of the andalusite-type structure. Combining all relevant mineral-chemical and petrological data available on the deposit, a speculative model is presented in which kanonaite crystals with successively higher Mn3+ contents form during decreasing temperatures in the course of the anticlockwise PTt path of extensional metamorphism. Kaolinite occurring in zones within composite kanonaite porphyroblasts of adjacent phyllites is regarded here as by-product of a continuous retrograde breakdown reaction of less manganiferous kanonaite. In places, kanonaite was peripherally replaced by muscovite and Mn- and Fe-oxides. [PUBLICATION ABSTRACT]</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s00410-004-0557-3</doi></addata></record>
fulltext fulltext
identifier ISSN: 0010-7999
ispartof Contributions to mineralogy and petrology, 2004-05, Vol.147 (3), p.276
issn 0010-7999
1432-0967
language eng
recordid cdi_proquest_journals_208182488
source Springer Link
subjects Crystals
Kaolinite
Manganese
Metamorphism
Mineralogy
Minerals
Petrology
Quartz
Veins (geology)
title End-member ferrian kanonaite: An andalusite phase with one Al fully replaced by (Mn, Fe)3+ in a quartz vein from the Ardennes
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T19%3A32%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=End-member%20ferrian%20kanonaite:%20An%20andalusite%20phase%20with%20one%20Al%20fully%20replaced%20by%20(Mn,%20Fe)3+%20in%20a%20quartz%20vein%20from%20the%20Ardennes&rft.jtitle=Contributions%20to%20mineralogy%20and%20petrology&rft.au=Schreyer,%20Werner&rft.date=2004-05-01&rft.volume=147&rft.issue=3&rft.spage=276&rft.pages=276-&rft.issn=0010-7999&rft.eissn=1432-0967&rft.coden=CMPEAP&rft_id=info:doi/10.1007/s00410-004-0557-3&rft_dat=%3Cproquest%3E781983171%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-proquest_journals_2081824883%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=208182488&rft_id=info:pmid/&rfr_iscdi=true