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Glass Formation in the Ternary System La2O3–As2S3–Er2O3
The boundaries of the glass formation region in the ternary system La 2 O 3 –As 2 S 3 –Er 2 O 3 were found. Transparent glass of composition (La 2 O 3 ) 0.03 (As 2 S 3 )0.90(Er 2 O 3 )0.07 was studied by X-ray photoelectron and Raman spectroscopy. The intensities of the bands characterizing As–S, La...
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| Published in: | Russian journal of inorganic chemistry 2018-07, Vol.63 (7), p.962-965 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 965 |
| container_issue | 7 |
| container_start_page | 962 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 63 |
| creator | Bakhtiyarly, I. B. Fatullaeva, G. M. Kerimli, O. Sh |
| description | The boundaries of the glass formation region in the ternary system La
2
O
3
–As
2
S
3
–Er
2
O
3
were found. Transparent glass of composition (La
2
O
3
)
0.03
(As
2
S
3
)0.90(Er
2
O
3
)0.07 was studied by X-ray photoelectron and Raman spectroscopy. The intensities of the bands characterizing As–S, La–O, and Er–O bonds increased, and these bands were shifted toward higher energies. This was due to an increase in the covalence of these bonds and probably due to the formation of new bonds in the glasses. Samples in the glass formation region are resistant at 300 K to air, water, and organic solvents. |
| doi_str_mv | 10.1134/S0036023618070021 |
| format | article |
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2
O
3
–As
2
S
3
–Er
2
O
3
were found. Transparent glass of composition (La
2
O
3
)
0.03
(As
2
S
3
)0.90(Er
2
O
3
)0.07 was studied by X-ray photoelectron and Raman spectroscopy. The intensities of the bands characterizing As–S, La–O, and Er–O bonds increased, and these bands were shifted toward higher energies. This was due to an increase in the covalence of these bonds and probably due to the formation of new bonds in the glasses. Samples in the glass formation region are resistant at 300 K to air, water, and organic solvents.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023618070021</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Arsenic trisulfide ; Bonding ; Chemistry ; Chemistry and Materials Science ; Erbium oxide ; Glass formation ; Inorganic Chemistry ; Lanthanum oxides ; Physicochemical Analysis of Inorganic Systems ; Ternary systems</subject><ispartof>Russian journal of inorganic chemistry, 2018-07, Vol.63 (7), p.962-965</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-cced7a347c26d49258b774cf0d59e61feef24151dc0e9d29b5e0b55da3b533333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Bakhtiyarly, I. B.</creatorcontrib><creatorcontrib>Fatullaeva, G. M.</creatorcontrib><creatorcontrib>Kerimli, O. Sh</creatorcontrib><title>Glass Formation in the Ternary System La2O3–As2S3–Er2O3</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The boundaries of the glass formation region in the ternary system La
2
O
3
–As
2
S
3
–Er
2
O
3
were found. Transparent glass of composition (La
2
O
3
)
0.03
(As
2
S
3
)0.90(Er
2
O
3
)0.07 was studied by X-ray photoelectron and Raman spectroscopy. The intensities of the bands characterizing As–S, La–O, and Er–O bonds increased, and these bands were shifted toward higher energies. This was due to an increase in the covalence of these bonds and probably due to the formation of new bonds in the glasses. Samples in the glass formation region are resistant at 300 K to air, water, and organic solvents.</description><subject>Arsenic trisulfide</subject><subject>Bonding</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Erbium oxide</subject><subject>Glass formation</subject><subject>Inorganic Chemistry</subject><subject>Lanthanum oxides</subject><subject>Physicochemical Analysis of Inorganic Systems</subject><subject>Ternary systems</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKw1AQvYiCsfoB7gKuozP3kdzgqpS2CoUuUtfhJploSh713nTRnf_gH_olJkRwIc7mMJwHM4exW4R7RCEfEgARAhchaogAOJ4xD5XAQIcozpk30sHIX7Ir5_YAUkKkPfa4ro1z_qqzjemrrvWr1u_fyN-RbY09-cnJ9dT4G8O34uvjc-54MuLSDvs1uyhN7ejmB2fsZbXcLZ6CzXb9vJhvgpyHug_ynIrICBkNayFjrnQWRTIvoVAxhVgSlVyiwiIHigseZ4ogU6owIlNinBm7m3IPtns_kuvTfXcczqtdykFzVBr0qMJJldvOOUtlerBVM_yQIqRjR-mfjgYPnzxu0LavZH-T_zd9A-GvZyc</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Bakhtiyarly, I. B.</creator><creator>Fatullaeva, G. M.</creator><creator>Kerimli, O. Sh</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180701</creationdate><title>Glass Formation in the Ternary System La2O3–As2S3–Er2O3</title><author>Bakhtiyarly, I. B. ; Fatullaeva, G. M. ; Kerimli, O. Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-cced7a347c26d49258b774cf0d59e61feef24151dc0e9d29b5e0b55da3b533333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Arsenic trisulfide</topic><topic>Bonding</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Erbium oxide</topic><topic>Glass formation</topic><topic>Inorganic Chemistry</topic><topic>Lanthanum oxides</topic><topic>Physicochemical Analysis of Inorganic Systems</topic><topic>Ternary systems</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bakhtiyarly, I. B.</creatorcontrib><creatorcontrib>Fatullaeva, G. M.</creatorcontrib><creatorcontrib>Kerimli, O. Sh</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bakhtiyarly, I. B.</au><au>Fatullaeva, G. M.</au><au>Kerimli, O. Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Glass Formation in the Ternary System La2O3–As2S3–Er2O3</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>63</volume><issue>7</issue><spage>962</spage><epage>965</epage><pages>962-965</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The boundaries of the glass formation region in the ternary system La
2
O
3
–As
2
S
3
–Er
2
O
3
were found. Transparent glass of composition (La
2
O
3
)
0.03
(As
2
S
3
)0.90(Er
2
O
3
)0.07 was studied by X-ray photoelectron and Raman spectroscopy. The intensities of the bands characterizing As–S, La–O, and Er–O bonds increased, and these bands were shifted toward higher energies. This was due to an increase in the covalence of these bonds and probably due to the formation of new bonds in the glasses. Samples in the glass formation region are resistant at 300 K to air, water, and organic solvents.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023618070021</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2018-07, Vol.63 (7), p.962-965 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2082158083 |
| source | Springer Nature |
| subjects | Arsenic trisulfide Bonding Chemistry Chemistry and Materials Science Erbium oxide Glass formation Inorganic Chemistry Lanthanum oxides Physicochemical Analysis of Inorganic Systems Ternary systems |
| title | Glass Formation in the Ternary System La2O3–As2S3–Er2O3 |
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