Determination of bromide in aqueous solutions via the TlBr molecule using high-resolution continuum source graphite furnace molecular absorption spectrometry

• Published in: Spectrochimica acta. Part B: Atomic spectroscopy 2018-06, Vol.144, p.63-67
• Main Authors: Cacho, Frantisek, Machynak, Lubomir, Nemecek, Martin, Beinrohr, Ernest
• Format: Article
• Language: English
• Subjects: Absorption; Absorption spectroscopy; Adsorption; Aqueous solutions; Atomic absorption analysis; Bromide; Calibration; Correlation coefficient; Correlation coefficients; Detection; Drinking water; Graphite; High resolution; HR-CS GF MAS; Methods; Molecular absorption; Organic chemistry; Palladium; Pyrolysis; Resolution; Silver; Solutions; Spectral analysis; Spectrometry; Temperature; Thallium; Water analysis; Water sampling; Wavelength
• ISSN: 0584-8547; 1873-3565
• DOI: 10.1016/j.sab.2018.03.010

The paper describes the determination of bromide by evaluating the molecular absorption of thallium mono-bromide (TlBr) at the rotational line at 342.9815nm by making use a high-resolution continuum source graphite furnace atomic absorption spectrometer. The effects of variables such as the wavelength, graphite furnace program, amount of Tl and the use of a modifier were investigated and optimized. Various chemical modifiers have been studied, such as Pd, Mg, Ag and a mixture of Pd/Mg. It was found that best results were obtained by using Ag which prevents losses of bromide during pyrolysis step through precipitation of bromide as AgBr. In this way, a maximum pyrolysis temperature of 400°C could be used. The optimum molecule forming temperature was found to be 900°C. Bromide concentrations in various water samples (CRM, bottled drinking water and tap water) were determined. The quantification was made by both linear calibration and standard addition techniques. The results were matched well those of the reference method. The calibration curve was linear in the range between 1 and 1000ng Br with a correlation coefficient R=0.999. The limit of detection and characteristic mass of the method were 0.3ng and 4.4ng of Br. [Display omitted] •HR-CS MAS as technique for Br determination via TlBr molecule was used.•The use of Ag as a modifier enabled a significant increase of analytical signal.•The limit of detection and characteristic mass for Br were 0.3ng and 4.4ng, respectively.•A good linearity is maintained up to 1μg of Br.