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Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand
A new cadmium(II) and a new cobalt(II) coordination complexes [Cd 5 (BTB) 4 (HL) 2 ]·2H 2 O ( 1 ) and [Co(HBTB)(L)]·2H 2 O ( 2 ) [H 3 BTB = 1,3,5-tri(4-carboxylphenyl)benzene, L = N,N′ -bis(3-pyridyl)octandiamide] were prepared under the solvothermal conditions by the assembly of cadmium(II)/cobalt...
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| Published in: | Journal of inorganic and organometallic polymers and materials 2018-09, Vol.28 (5), p.1810-1820 |
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| cites | cdi_FETCH-LOGICAL-c353t-14ab67a7e5890f712f420d878084222b63211d5ce31e1df1445adee992c2fa623 |
| container_end_page | 1820 |
| container_issue | 5 |
| container_start_page | 1810 |
| container_title | Journal of inorganic and organometallic polymers and materials |
| container_volume | 28 |
| creator | Lin, HongYan Cui, ZiWei Tian, Yuan Wang, Xiang Liu, GuoCheng |
| description | A new cadmium(II) and a new cobalt(II) coordination complexes [Cd
5
(BTB)
4
(HL)
2
]·2H
2
O (
1
) and [Co(HBTB)(L)]·2H
2
O (
2
) [H
3
BTB = 1,3,5-tri(4-carboxylphenyl)benzene, L =
N,N′
-bis(3-pyridyl)octandiamide] were prepared under the solvothermal conditions by the assembly of cadmium(II)/cobalt(II) chloride, the flexible bis(pyridyl)-bis(amide) ligand L and the aromatic tricarboxylic acid H
3
BTB. The structures of complexes
1
–
2
have been characterized by X-ray single crystal diffraction analyses, infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric (TG) analyses. Complex
1
is a 3D metal–organic network with the penta-nodal (2,4,4,5,6)-connected {4·6
3
·8·10}
2
{4
2
·6
5
·8
3
}
2
{4
3
·6
3
}
2
{4
6
·8
9
}{6}
2
topology constructed from the 3D [Cd
5
(BTB)
4
]
n
2n−
coordiantion framework and the protonated HL ligands. Complex
2
displays a binodal (4,4)-connected {6
4
·8·10}{6} topological 2D layered architecture based on the 1D [Co(HBTB)]
n
chains and the 1D [CoL]
n
chains, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Moreover, the fluorescent properties of the cadmium(II) complex and the dyes adsorption performances of complexes
1
–
2
have been studied. |
| doi_str_mv | 10.1007/s10904-018-0829-4 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2082708910</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2082708910</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-14ab67a7e5890f712f420d878084222b63211d5ce31e1df1445adee992c2fa623</originalsourceid><addsrcrecordid>eNp1kVFPgzAQx4nRxDn9AL418WVLxLUFBjwicbpkiXuYz02hx-wCFFuIw4_jJ7WI0Sef7q75_-6u93eca4LvCMbhwhAcY9_FJHJxRGPXP3EmJAh9l_gBOf3Nfe_cuTDmgLEX4YBMnM_EGKiysr9Fq7JTGkwOdYt4LVAijNJNK1WNtlo1oFsJBqkC7d4VSrmoZFfN1uv5IlUZL9shRalSWsiaf1OpqpoSjhZadXU-PPFSfoBAWY_aV7AD4SizEtC9NLNtr6Xoy7mb2SKppIA52si9XeTSOSt4aeDqJ06dl9XDLn1yN8-P6zTZuLkXeK39HM-WIQ8hiGJchIQWPsUiCiMc-ZTSbOlRQkSQg0eAiMLeIuACII5pTgu-pN7UuRn7Nlq9dWBadlCdtjsbRu1NQxzFBFsVGVW5VsZoKFijZcV1zwhmgxVstIJZK9hgBfMtQ0fGWG29B_3X-X_oCx_XjF8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2082708910</pqid></control><display><type>article</type><title>Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand</title><source>Springer Link</source><creator>Lin, HongYan ; Cui, ZiWei ; Tian, Yuan ; Wang, Xiang ; Liu, GuoCheng</creator><creatorcontrib>Lin, HongYan ; Cui, ZiWei ; Tian, Yuan ; Wang, Xiang ; Liu, GuoCheng</creatorcontrib><description>A new cadmium(II) and a new cobalt(II) coordination complexes [Cd
5
(BTB)
4
(HL)
2
]·2H
2
O (
1
) and [Co(HBTB)(L)]·2H
2
O (
2
) [H
3
BTB = 1,3,5-tri(4-carboxylphenyl)benzene, L =
N,N′
-bis(3-pyridyl)octandiamide] were prepared under the solvothermal conditions by the assembly of cadmium(II)/cobalt(II) chloride, the flexible bis(pyridyl)-bis(amide) ligand L and the aromatic tricarboxylic acid H
3
BTB. The structures of complexes
1
–
2
have been characterized by X-ray single crystal diffraction analyses, infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric (TG) analyses. Complex
1
is a 3D metal–organic network with the penta-nodal (2,4,4,5,6)-connected {4·6
3
·8·10}
2
{4
2
·6
5
·8
3
}
2
{4
3
·6
3
}
2
{4
6
·8
9
}{6}
2
topology constructed from the 3D [Cd
5
(BTB)
4
]
n
2n−
coordiantion framework and the protonated HL ligands. Complex
2
displays a binodal (4,4)-connected {6
4
·8·10}{6} topological 2D layered architecture based on the 1D [Co(HBTB)]
n
chains and the 1D [CoL]
n
chains, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Moreover, the fluorescent properties of the cadmium(II) complex and the dyes adsorption performances of complexes
1
–
2
have been studied.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-018-0829-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Adsorption ; Assembly ; Benzene ; Cadmium ; Chains ; Chemistry ; Chemistry and Materials Science ; Cobalt ; Coordination compounds ; Fluorescence ; Hydrogen bonding ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Ligands ; Organic Chemistry ; Polymer Sciences ; Single crystals ; Topology ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2018-09, Vol.28 (5), p.1810-1820</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-14ab67a7e5890f712f420d878084222b63211d5ce31e1df1445adee992c2fa623</citedby><cites>FETCH-LOGICAL-c353t-14ab67a7e5890f712f420d878084222b63211d5ce31e1df1445adee992c2fa623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Lin, HongYan</creatorcontrib><creatorcontrib>Cui, ZiWei</creatorcontrib><creatorcontrib>Tian, Yuan</creatorcontrib><creatorcontrib>Wang, Xiang</creatorcontrib><creatorcontrib>Liu, GuoCheng</creatorcontrib><title>Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A new cadmium(II) and a new cobalt(II) coordination complexes [Cd
5
(BTB)
4
(HL)
2
]·2H
2
O (
1
) and [Co(HBTB)(L)]·2H
2
O (
2
) [H
3
BTB = 1,3,5-tri(4-carboxylphenyl)benzene, L =
N,N′
-bis(3-pyridyl)octandiamide] were prepared under the solvothermal conditions by the assembly of cadmium(II)/cobalt(II) chloride, the flexible bis(pyridyl)-bis(amide) ligand L and the aromatic tricarboxylic acid H
3
BTB. The structures of complexes
1
–
2
have been characterized by X-ray single crystal diffraction analyses, infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric (TG) analyses. Complex
1
is a 3D metal–organic network with the penta-nodal (2,4,4,5,6)-connected {4·6
3
·8·10}
2
{4
2
·6
5
·8
3
}
2
{4
3
·6
3
}
2
{4
6
·8
9
}{6}
2
topology constructed from the 3D [Cd
5
(BTB)
4
]
n
2n−
coordiantion framework and the protonated HL ligands. Complex
2
displays a binodal (4,4)-connected {6
4
·8·10}{6} topological 2D layered architecture based on the 1D [Co(HBTB)]
n
chains and the 1D [CoL]
n
chains, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Moreover, the fluorescent properties of the cadmium(II) complex and the dyes adsorption performances of complexes
1
–
2
have been studied.</description><subject>Adsorption</subject><subject>Assembly</subject><subject>Benzene</subject><subject>Cadmium</subject><subject>Chains</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Coordination compounds</subject><subject>Fluorescence</subject><subject>Hydrogen bonding</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Single crystals</subject><subject>Topology</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kVFPgzAQx4nRxDn9AL418WVLxLUFBjwicbpkiXuYz02hx-wCFFuIw4_jJ7WI0Sef7q75_-6u93eca4LvCMbhwhAcY9_FJHJxRGPXP3EmJAh9l_gBOf3Nfe_cuTDmgLEX4YBMnM_EGKiysr9Fq7JTGkwOdYt4LVAijNJNK1WNtlo1oFsJBqkC7d4VSrmoZFfN1uv5IlUZL9shRalSWsiaf1OpqpoSjhZadXU-PPFSfoBAWY_aV7AD4SizEtC9NLNtr6Xoy7mb2SKppIA52si9XeTSOSt4aeDqJ06dl9XDLn1yN8-P6zTZuLkXeK39HM-WIQ8hiGJchIQWPsUiCiMc-ZTSbOlRQkSQg0eAiMLeIuACII5pTgu-pN7UuRn7Nlq9dWBadlCdtjsbRu1NQxzFBFsVGVW5VsZoKFijZcV1zwhmgxVstIJZK9hgBfMtQ0fGWG29B_3X-X_oCx_XjF8</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Lin, HongYan</creator><creator>Cui, ZiWei</creator><creator>Tian, Yuan</creator><creator>Wang, Xiang</creator><creator>Liu, GuoCheng</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180901</creationdate><title>Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand</title><author>Lin, HongYan ; Cui, ZiWei ; Tian, Yuan ; Wang, Xiang ; Liu, GuoCheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-14ab67a7e5890f712f420d878084222b63211d5ce31e1df1445adee992c2fa623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adsorption</topic><topic>Assembly</topic><topic>Benzene</topic><topic>Cadmium</topic><topic>Chains</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Coordination compounds</topic><topic>Fluorescence</topic><topic>Hydrogen bonding</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Single crystals</topic><topic>Topology</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, HongYan</creatorcontrib><creatorcontrib>Cui, ZiWei</creatorcontrib><creatorcontrib>Tian, Yuan</creatorcontrib><creatorcontrib>Wang, Xiang</creatorcontrib><creatorcontrib>Liu, GuoCheng</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, HongYan</au><au>Cui, ZiWei</au><au>Tian, Yuan</au><au>Wang, Xiang</au><au>Liu, GuoCheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2018-09-01</date><risdate>2018</risdate><volume>28</volume><issue>5</issue><spage>1810</spage><epage>1820</epage><pages>1810-1820</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A new cadmium(II) and a new cobalt(II) coordination complexes [Cd
5
(BTB)
4
(HL)
2
]·2H
2
O (
1
) and [Co(HBTB)(L)]·2H
2
O (
2
) [H
3
BTB = 1,3,5-tri(4-carboxylphenyl)benzene, L =
N,N′
-bis(3-pyridyl)octandiamide] were prepared under the solvothermal conditions by the assembly of cadmium(II)/cobalt(II) chloride, the flexible bis(pyridyl)-bis(amide) ligand L and the aromatic tricarboxylic acid H
3
BTB. The structures of complexes
1
–
2
have been characterized by X-ray single crystal diffraction analyses, infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric (TG) analyses. Complex
1
is a 3D metal–organic network with the penta-nodal (2,4,4,5,6)-connected {4·6
3
·8·10}
2
{4
2
·6
5
·8
3
}
2
{4
3
·6
3
}
2
{4
6
·8
9
}{6}
2
topology constructed from the 3D [Cd
5
(BTB)
4
]
n
2n−
coordiantion framework and the protonated HL ligands. Complex
2
displays a binodal (4,4)-connected {6
4
·8·10}{6} topological 2D layered architecture based on the 1D [Co(HBTB)]
n
chains and the 1D [CoL]
n
chains, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Moreover, the fluorescent properties of the cadmium(II) complex and the dyes adsorption performances of complexes
1
–
2
have been studied.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-018-0829-4</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2018-09, Vol.28 (5), p.1810-1820 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_journals_2082708910 |
| source | Springer Link |
| subjects | Adsorption Assembly Benzene Cadmium Chains Chemistry Chemistry and Materials Science Cobalt Coordination compounds Fluorescence Hydrogen bonding Infrared analysis Infrared spectroscopy Inorganic Chemistry Ligands Organic Chemistry Polymer Sciences Single crystals Topology X ray powder diffraction X-ray diffraction |
| title | Assembly, Fluorescent and Adsorption Properties of Two Cadmium(II)/Cobalt(II) Coordination Complexes Functionalized by the Flexible Bis(Pyridyl)-bis(Amide) Ligand |
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