Inverse Melting of an Electronic Liquid Crystal

Inverse melting refers to the rare thermodynamic phenomenon in which a solid melts into a liquid upon cooling, a transition that can occur only when the ordered (solid) phase has more entropy than the disordered (liquid) phase, and that has so far only been observed in a handful of systems. Here we...

Full description

Saved in:
Bibliographic Details
Published in:arXiv.org 2014-10
Main Authors: Shu-Han, Lee, Yen-Chung, Lai, Chao-Hung, Du, Kao, Ying-Jer, Siegenfeld, Alexander F, Hatton, Peter D, Prabhakaran, D, Su, Yixi, Di-Jing, Huang
Format: Article
Language:English
Subjects:
Cuprates
Electronic systems
Interlayers
Lanthanum
Liquid crystals
Melting
Melts
Strontium
Variation
X-ray scattering
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Inverse melting refers to the rare thermodynamic phenomenon in which a solid melts into a liquid upon cooling, a transition that can occur only when the ordered (solid) phase has more entropy than the disordered (liquid) phase, and that has so far only been observed in a handful of systems. Here we report the first experimental observation for the inverse melting of an electronic liquid crystalline order in strontium-doped lanthanum nickelate, a compound isostructural with the superconducting cuprates, with a hole doping concentration of 1/3. Using x-ray scattering, we demonstrate that the isotropic charge modulation is driven to nematic order by fluctuating spins and shows an inverse melting transition. Using a phenomenological Landau theory, we show that this inverse melting transition is due to the interlayer coupling between the charge and spin orders. This discovery points to the importance of the interlayer correlations in the system, and provides a new perspective to study the intricate nature of the electronic liquid crystal phases in strongly correlated electronic systems, including possibly the Cu- and Fe-based high-Tc superconductors.
ISSN:2331-8422