Regiospecific Bi‐Catalysed Domino C‐N/C‐S Bonds Formation: Synthesis of 1,4‐Thiazines/1,4‐Thiomorpholines

A domino Bi‐catalysed C−N/C−S bond formation of N‐sulfonylaziridines is developed with 1,4‐dithiane‐2,5‐diol to give 3,4‐dihydro‐1,4‐thiazines at room temperature. The use of Bi(OTf)3 as a catalyst, atom economy and regioselectivity are the important practical features.

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Published in:Advanced synthesis & catalysis 2018-08, Vol.360 (16), p.3030-3037
Main Authors: Vijay, Murugan, Satheesh, Vanaparthi, Kumar, Sundaravel Vivek, Punniyamurthy, Tharmalingam
Format: Article
Language:English
Subjects:
1,4-thiazine
1,4-thiomorpholine
Bi-catalysis
Chemical synthesis
domino
Regioselectivity
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description A domino Bi‐catalysed C−N/C−S bond formation of N‐sulfonylaziridines is developed with 1,4‐dithiane‐2,5‐diol to give 3,4‐dihydro‐1,4‐thiazines at room temperature. The use of Bi(OTf)3 as a catalyst, atom economy and regioselectivity are the important practical features.
doi_str_mv 10.1002/adsc.201800511
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subjects 1,4-thiazine
1,4-thiomorpholine
Bi-catalysis
Chemical synthesis
domino
Regioselectivity
title Regiospecific Bi‐Catalysed Domino C‐N/C‐S Bonds Formation: Synthesis of 1,4‐Thiazines/1,4‐Thiomorpholines
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