Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst

[Display omitted] •SiO2-ATS-PTA is a robust catalyst for HMF production from glucose.•Furfural was the main byproduct.•The reaction path was suggested. Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosph...

Full description

Saved in:
Bibliographic Details
Published in:Fuel (Guildford) 2018-08, Vol.226, p.417-422
Main Authors: Huang, Fangmin, Su, Yuwen, Tao, Yu, Sun, Wei, Wang, Weiting
Format: Article
Language:English
Subjects:
5-Hydroxymethylfurfural
Acids
Biomass
Carbohydrates
Catalysis
Catalysts
Catalytic activity
Conversion
Furfural
Glucose
Hydroxymethylfurfural
Kinetics
Phosphotungstic acid
Pyridines
Silica
Silica gel
Silicon dioxide
Studies
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263
cites cdi_FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263
container_end_page 422
container_issue
container_start_page 417
container_title Fuel (Guildford)
container_volume 226
creator Huang, Fangmin
Su, Yuwen
Tao, Yu
Sun, Wei
Wang, Weiting
description [Display omitted] •SiO2-ATS-PTA is a robust catalyst for HMF production from glucose.•Furfural was the main byproduct.•The reaction path was suggested. Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosphotungstic acid (PTA) heterogeneous catalyst (SiO2-ATS-PTA) was prepared and characterized by XRD, FT-IR, pyridine-FTIR and SEM. The SiO2-ATS-PTA was used to catalyze the conversion of glucose, and it afforded 78.31% yield of HMF at 160 °C for 140 min. The SiO2-ATS-PTA could be reused for five runs without significant loss of catalytic activity. Furfural was the main byproduct. A kinetic analysis was carried out and the values of the activation energy and the pre-exponential factor for the reaction were 30.25 kJ mol−1 and 1.08 × 107 min−1, respectively.
doi_str_mv 10.1016/j.fuel.2018.03.193
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2089867471</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0016236118306112</els_id><sourcerecordid>2089867471</sourcerecordid><originalsourceid>FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263</originalsourceid><addsrcrecordid>eNp9kE1LxDAQhoMouH78AU8Bz61J0zYteJHFLxD0oOeQJpPdLN2mJqlYwf9ult2zMMPA8L7vDA9CV5TklND6ZpObCfq8ILTJCctpy47QgjacZZxW7BgtSFJlBavpKToLYUMI4U1VLtDvm4dRehmtG7AzuMrWs_bue95CXM-9mXwq2WPj3Rav-km5AFjJKPv5BzTuZhxsb5XMwjSOzse0G9cupI7TsArRKiyV1XgNEbxbwQBuCoeAEC_QiZF9gMvDPEcfD_fvy6fs5fXxeXn3kqmS0Zhxo2teMEbalpedBFNSI9tKG8INQKe1qU3RtWVJQRYVo1TyRhtJus400hQ1O0fX-9zRu88JQhQbN_khnRQFadqm5iWnSVXsVcq7EDwYMXq7lX4WlIgdZrERO8xih1kQJhLmZLrdmyD9_2XBi6AsDAq09aCi0M7-Z_8DbWeLcg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2089867471</pqid></control><display><type>article</type><title>Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst</title><source>ScienceDirect Freedom Collection 2022-2024</source><creator>Huang, Fangmin ; Su, Yuwen ; Tao, Yu ; Sun, Wei ; Wang, Weiting</creator><creatorcontrib>Huang, Fangmin ; Su, Yuwen ; Tao, Yu ; Sun, Wei ; Wang, Weiting</creatorcontrib><description>[Display omitted] •SiO2-ATS-PTA is a robust catalyst for HMF production from glucose.•Furfural was the main byproduct.•The reaction path was suggested. Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosphotungstic acid (PTA) heterogeneous catalyst (SiO2-ATS-PTA) was prepared and characterized by XRD, FT-IR, pyridine-FTIR and SEM. The SiO2-ATS-PTA was used to catalyze the conversion of glucose, and it afforded 78.31% yield of HMF at 160 °C for 140 min. The SiO2-ATS-PTA could be reused for five runs without significant loss of catalytic activity. Furfural was the main byproduct. A kinetic analysis was carried out and the values of the activation energy and the pre-exponential factor for the reaction were 30.25 kJ mol−1 and 1.08 × 107 min−1, respectively.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2018.03.193</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>5-Hydroxymethylfurfural ; Acids ; Biomass ; Carbohydrates ; Catalysis ; Catalysts ; Catalytic activity ; Conversion ; Furfural ; Glucose ; Hydroxymethylfurfural ; Kinetics ; Phosphotungstic acid ; Pyridines ; Silica ; Silica gel ; Silicon dioxide ; Studies</subject><ispartof>Fuel (Guildford), 2018-08, Vol.226, p.417-422</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV Aug 15, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263</citedby><cites>FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Huang, Fangmin</creatorcontrib><creatorcontrib>Su, Yuwen</creatorcontrib><creatorcontrib>Tao, Yu</creatorcontrib><creatorcontrib>Sun, Wei</creatorcontrib><creatorcontrib>Wang, Weiting</creatorcontrib><title>Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst</title><title>Fuel (Guildford)</title><description>[Display omitted] •SiO2-ATS-PTA is a robust catalyst for HMF production from glucose.•Furfural was the main byproduct.•The reaction path was suggested. Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosphotungstic acid (PTA) heterogeneous catalyst (SiO2-ATS-PTA) was prepared and characterized by XRD, FT-IR, pyridine-FTIR and SEM. The SiO2-ATS-PTA was used to catalyze the conversion of glucose, and it afforded 78.31% yield of HMF at 160 °C for 140 min. The SiO2-ATS-PTA could be reused for five runs without significant loss of catalytic activity. Furfural was the main byproduct. A kinetic analysis was carried out and the values of the activation energy and the pre-exponential factor for the reaction were 30.25 kJ mol−1 and 1.08 × 107 min−1, respectively.</description><subject>5-Hydroxymethylfurfural</subject><subject>Acids</subject><subject>Biomass</subject><subject>Carbohydrates</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Conversion</subject><subject>Furfural</subject><subject>Glucose</subject><subject>Hydroxymethylfurfural</subject><subject>Kinetics</subject><subject>Phosphotungstic acid</subject><subject>Pyridines</subject><subject>Silica</subject><subject>Silica gel</subject><subject>Silicon dioxide</subject><subject>Studies</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouH78AU8Bz61J0zYteJHFLxD0oOeQJpPdLN2mJqlYwf9ult2zMMPA8L7vDA9CV5TklND6ZpObCfq8ILTJCctpy47QgjacZZxW7BgtSFJlBavpKToLYUMI4U1VLtDvm4dRehmtG7AzuMrWs_bue95CXM-9mXwq2WPj3Rav-km5AFjJKPv5BzTuZhxsb5XMwjSOzse0G9cupI7TsArRKiyV1XgNEbxbwQBuCoeAEC_QiZF9gMvDPEcfD_fvy6fs5fXxeXn3kqmS0Zhxo2teMEbalpedBFNSI9tKG8INQKe1qU3RtWVJQRYVo1TyRhtJus400hQ1O0fX-9zRu88JQhQbN_khnRQFadqm5iWnSVXsVcq7EDwYMXq7lX4WlIgdZrERO8xih1kQJhLmZLrdmyD9_2XBi6AsDAq09aCi0M7-Z_8DbWeLcg</recordid><startdate>20180815</startdate><enddate>20180815</enddate><creator>Huang, Fangmin</creator><creator>Su, Yuwen</creator><creator>Tao, Yu</creator><creator>Sun, Wei</creator><creator>Wang, Weiting</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20180815</creationdate><title>Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst</title><author>Huang, Fangmin ; Su, Yuwen ; Tao, Yu ; Sun, Wei ; Wang, Weiting</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>5-Hydroxymethylfurfural</topic><topic>Acids</topic><topic>Biomass</topic><topic>Carbohydrates</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Conversion</topic><topic>Furfural</topic><topic>Glucose</topic><topic>Hydroxymethylfurfural</topic><topic>Kinetics</topic><topic>Phosphotungstic acid</topic><topic>Pyridines</topic><topic>Silica</topic><topic>Silica gel</topic><topic>Silicon dioxide</topic><topic>Studies</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Fangmin</creatorcontrib><creatorcontrib>Su, Yuwen</creatorcontrib><creatorcontrib>Tao, Yu</creatorcontrib><creatorcontrib>Sun, Wei</creatorcontrib><creatorcontrib>Wang, Weiting</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts – Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Fangmin</au><au>Su, Yuwen</au><au>Tao, Yu</au><au>Sun, Wei</au><au>Wang, Weiting</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst</atitle><jtitle>Fuel (Guildford)</jtitle><date>2018-08-15</date><risdate>2018</risdate><volume>226</volume><spage>417</spage><epage>422</epage><pages>417-422</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>[Display omitted] •SiO2-ATS-PTA is a robust catalyst for HMF production from glucose.•Furfural was the main byproduct.•The reaction path was suggested. Conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) is a valuable reaction for biomass efficient utilization. The silica-supported phosphotungstic acid (PTA) heterogeneous catalyst (SiO2-ATS-PTA) was prepared and characterized by XRD, FT-IR, pyridine-FTIR and SEM. The SiO2-ATS-PTA was used to catalyze the conversion of glucose, and it afforded 78.31% yield of HMF at 160 °C for 140 min. The SiO2-ATS-PTA could be reused for five runs without significant loss of catalytic activity. Furfural was the main byproduct. A kinetic analysis was carried out and the values of the activation energy and the pre-exponential factor for the reaction were 30.25 kJ mol−1 and 1.08 × 107 min−1, respectively.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2018.03.193</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0016-2361
ispartof Fuel (Guildford), 2018-08, Vol.226, p.417-422
issn 0016-2361
1873-7153
language eng
recordid cdi_proquest_journals_2089867471
source ScienceDirect Freedom Collection 2022-2024
subjects 5-Hydroxymethylfurfural
Acids
Biomass
Carbohydrates
Catalysis
Catalysts
Catalytic activity
Conversion
Furfural
Glucose
Hydroxymethylfurfural
Kinetics
Phosphotungstic acid
Pyridines
Silica
Silica gel
Silicon dioxide
Studies
title Preparation of 5-hydroxymethylfurfural from glucose catalyzed by silica-supported phosphotungstic acid heterogeneous catalyst
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T15%3A42%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20of%205-hydroxymethylfurfural%20from%20glucose%20catalyzed%20by%20silica-supported%20phosphotungstic%20acid%20heterogeneous%20catalyst&rft.jtitle=Fuel%20(Guildford)&rft.au=Huang,%20Fangmin&rft.date=2018-08-15&rft.volume=226&rft.spage=417&rft.epage=422&rft.pages=417-422&rft.issn=0016-2361&rft.eissn=1873-7153&rft_id=info:doi/10.1016/j.fuel.2018.03.193&rft_dat=%3Cproquest_cross%3E2089867471%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c431t-7fd6723309974baef41fa95df07feebddf6f2b9441ea25311a78dfa0bbf8af263%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2089867471&rft_id=info:pmid/&rfr_iscdi=true