Impact of Zn substitution on phase formation and superconductivity of Bi1.6Pb0.4 Sr2Ca2Cu3-xZnxO10 with x = 0.0, 0.015, 0.03, 0.06, 0.09 and 0.12

• Published in: arXiv.org 2005-05
• Main Authors: Saxena, R B, Giri, Rajiv, Awana, V P S, Singh, H K, Ansari, M A, Kumaraswamy, B V, Gupta, Anurag, Rashmi Nigam1, Singh, K P, Kishan, H, Srivastava, O N
• Format: Article
• Language: English
• Subjects: Bismuth strontium calcium copper oxide; Chemical synthesis; High temperature; Lattice parameters; Magnetic permeability; Phase transitions; Substitution reactions; Superconductivity; Transition temperature; Zinc
• ISSN: 2331-8422
• DOI: 10.48550/arxiv.0505461

Samples of series Bi1.6Pb0.4Sr2Ca2Cu3-xZnxO10 with x = 0.0, 0.015, 0.03, 0.06, 0.09 and 0.12 are synthesized by solid-state reaction route. All the samples crystallize in tetragonal structure with majority (> 90%) of Bi-2223 (Bi2Sr2Ca2Cu3O10) phase (c-lattice parameter ~ 36 A0). The proportion of Bi-2223 phase decreases slightly with an increase in x. The lattice parameters a and c of main phase (Bi-2223) do not change significantly with increasing x. Superconducting critical transition temperature (Tc) decreases with x as evidenced by both resistivity [(T)] and AC magnetic susceptibility [(T)] measurements. Interestingly the decrement of Tc is not monotonic and the same saturates at around 96 K for x > 0.06. In fact Tc decreases fast (~10K/at%) for x = 0.015 and 0.03 samples and later nearly saturates for higher x values. Present results of Zn doping in Bi-2223 system are compared with Zn doped other HTSC (High temperature superconducting) systems, namely the RE-123 (REBa2Cu3O7) and La-214 ((La,Sr)2CuO4).