Ultrasound-assisted rapid synthesis of [beta]-cyanoepoxides using hypervalent iodine reagents

An elegant approach for the rapid synthesis of [beta]-cyanoepoxides 3 by the epoxidation of [beta]-cyanostyrenes 1 with PIDA 2a is described. The epoxidation of [beta]-cyanostyrenes 1 was performed with 1.2 equiv. of PIDA 2a in MeCN-H2O (1:1) at room temperature in ultrasonic bath. The epoxidation r...

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Published in:Synthetic communications 2018-09, Vol.48 (17), p.2169
Main Authors: Singh, Fateh V, Mangaonkar, Saeesh R, Kole, Priyanka B
Format: Article
Language:English
Subjects:
Cyanostyrene
Epoxidation
Iodine
Reaction time
Reagents
Synthesis
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creator Singh, Fateh V
Mangaonkar, Saeesh R
Kole, Priyanka B
description An elegant approach for the rapid synthesis of [beta]-cyanoepoxides 3 by the epoxidation of [beta]-cyanostyrenes 1 with PIDA 2a is described. The epoxidation of [beta]-cyanostyrenes 1 was performed with 1.2 equiv. of PIDA 2a in MeCN-H2O (1:1) at room temperature in ultrasonic bath. The epoxidation reactions were completed in short reaction time and [beta]-cyanoepoxides 3 were isolated in 69-94% yields.
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subjects Cyanostyrene
Epoxidation
Iodine
Reaction time
Reagents
Synthesis
title Ultrasound-assisted rapid synthesis of [beta]-cyanoepoxides using hypervalent iodine reagents
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