Photoreduction of 9,10-Phenanthrenequinone in the Presence of Dimethacrylate Oligomers and Their Polymers

The effective rate constants for the photoreduction ( k H ) of 9,10-phenanthrenequinone (PQ) in the presence of dimethacrylate monomers (ethylene glycol dimethacrylate (DMEG), triethylene glycol dimethacrylate (TGM-3), and oligocarbonate dimethacrylate (OKM-2)) and porous polymers based on them have...

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Bibliographic Details
Published in:High energy chemistry 2018-09, Vol.52 (5), p.378-383
Main Authors: Len’shina, N. A., Zakharina, M. Yu, Kovylin, R. S., Baten’kin, M. A., Kulikova, T. I., Arsen’ev, M. V., Chesnokov, S. A.
Format: Article
Language:English
Subjects:
Benzene
Chemistry
Chemistry and Materials Science
Ethylene glycol
Glycol dimethacrylates
Monomers
Photochemistry
Physical Chemistry
Polymers
Pore size
Rate constants
Spectrophotometry
Triethylene glycol dimethacrylate
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Summary:The effective rate constants for the photoreduction ( k H ) of 9,10-phenanthrenequinone (PQ) in the presence of dimethacrylate monomers (ethylene glycol dimethacrylate (DMEG), triethylene glycol dimethacrylate (TGM-3), and oligocarbonate dimethacrylate (OKM-2)) and porous polymers based on them have been spectrophotometrically determined. The values of k H in the presence of DMEG and TGM-3 in benzene solutions and in the monomer media are two times greater than in the presence of OKM-2. The values of k H for PQ in pores of polyDMEG, polyTGM-3, and polyOKM-2 are approximately identical and do not depend on the pore size (up to hundreds of nanometers) and the specific surface area.
ISSN:0018-1439
1608-3148
DOI:10.1134/S0018143918050090