Oxidative cyanide-free cyanation on arylboronic acid derivatives using aryl/heteroaryl thiocyanate using novel IL-PdCl4 catalyst under mild condition

An efficient and simple method is reported for the cyanation on arylboronic acid using various simple/indole thiocyanates using a new IL-PdCl 4 catalyst. The cascade process involves a coupling reaction without any additive to give a wide range of cyanide derivatives. Cyanation on various arylboroni...

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Bibliographic Details
Published in:Journal of sulfur chemistry 2018-09, Vol.39 (5), p.507-515
Main Authors: Vaghasiya, Beena K., Satasia, Shailesh P., Thummar, Rahul P., Kamani, Ronak D., Avalani, Jemin R., Sapariya, Nirav H., Raval, Dipak K.
Format: Article
Language:English
Subjects:
arylboronic acid
FE-SEM
IL-PdCl4
indoline derivatives
Thiocyanation
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Summary:An efficient and simple method is reported for the cyanation on arylboronic acid using various simple/indole thiocyanates using a new IL-PdCl 4 catalyst. The cascade process involves a coupling reaction without any additive to give a wide range of cyanide derivatives. Cyanation on various arylboronic acids underwent smoothly affording the corresponding arylnitriles in good to high yields.
ISSN:1741-5993
1741-6000
DOI:10.1080/17415993.2018.1469632