New Solvate Polymorphs of Lanthanide Trisacetylacetonates: Crystal Structures of [Ln(acac)3(H2O)2] · Solv (Ln = Eu, Dy; Solv = Thf, H2O + EtOH, MeOH)

Solvate polymorphs of [Dy(acac) 3 (H 2 O) 2 ] · Thf, [Ln(acac) 3 (H 2 O) 2 ] · H 2 O · EtOH (Ln = Eu, Dy) and [Dy(acac) 3 (H 2 O) 2 ] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography,...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2018-09, Vol.63 (9), p.1186-1191
Main Authors: Ilyukhin, A. B., Gavrikov, A. V., Dobrokhotova, Zh. V., Novotortsev, V. M.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Coordination Compounds
Crystal structure
Crystallography
Dysprosium
Inorganic Chemistry
Single crystals
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Summary:Solvate polymorphs of [Dy(acac) 3 (H 2 O) 2 ] · Thf, [Ln(acac) 3 (H 2 O) 2 ] · H 2 O · EtOH (Ln = Eu, Dy) and [Dy(acac) 3 (H 2 O) 2 ] · 1.5MeOH, which belongs to a new structural type, are isolated as single crystals. The structures of the prepared compounds are determined by X-ray crystallography, and the effect of solvate molecules on their crystal structures is discussed.
ISSN:0036-0236
1531-8613
DOI:10.1134/S003602361809005X