Polynuclear NiII and CoII hexafluoroacetylacetonates

Hydrolysis of [M 4 (hfac) 4 (MeO) 4 (MeOH) 4 ] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni 7 (hfac) 6 (OH) 8 (H 2 O) 6 ]•2H 2 O, [Co 12 (hfac) 10 (OH) 14 (H 2 O) 8 ]•2H 2 O•2MePh, [Co 12 (hfac) 10 (OH) 14 (H 2 O) 4 (Me 2 CO) 4 ]•3PhM...

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Bibliographic Details
Published in:Russian chemical bulletin 2018, Vol.67 (7), p.1202-1205
Main Authors: Kuznetsova, O. V., Fursova, E. Yu, Letyagin, G. A., Romanenko, G. V., Ovcharenko, V. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Inorganic Chemistry
Organic Chemistry
X ray analysis
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Summary:Hydrolysis of [M 4 (hfac) 4 (MeO) 4 (MeOH) 4 ] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni 7 (hfac) 6 (OH) 8 (H 2 O) 6 ]•2H 2 O, [Co 12 (hfac) 10 (OH) 14 (H 2 O) 8 ]•2H 2 O•2MePh, [Co 12 (hfac) 10 (OH) 14 (H 2 O) 4 (Me 2 CO) 4 ]•3PhMe, and [Co 12 (hfac) 10 (OH) 14 (H 2 O) 6 (Me 2 CO) 2 ]•2H 2 O•2Me 2 CO, whose structures were confirmed by X-ray analysis.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-018-2202-8