Fluid modeling of radical species generation mechanism in dense methane-air mixture streamer discharge

• Published in: Physics of plasmas 2018-01, Vol.25 (1)
• Main Authors: Qian, Muyang, Li, Gui, Kang, Jinsong, Liu, Sanqiu, Ren, Chunsheng, Zhang, Jialiang, Wang, Dezhen
• Format: Article
• Language: English
• Subjects: Atmospheric models; Chemical reactions; Dielectric barrier discharge; Electric fields; Electrons; Ionization; Methane; Organic chemistry; Permittivity; Plasma; Plasma chemistry; Plasma physics; Radicals; Streamer gas discharge; Two dimensional models
• ISSN: 1070-664X; 1089-7674
• DOI: 10.1063/1.5016855

Atmospheric dielectric barrier discharge (DBD) was found to be promising in the context of plasma chemistry, plasma medicine, and plasma-assisted combustion. In this paper, we present a detailed fluid modeling study of abundant radical species produced by a positive streamer in atmospheric dense methane-air DBD. A two-dimensional axisymmetric fluid model is constructed, in which 82 plasma chemical reactions and 30 different species are considered. Spatial and temporal density distributions of dominant radicals and ions are presented. We lay our emphasis on the effect of varying relative permittivity (εr = 2, 4.5, and 9) on the streamer dynamics in the plasma column, such as electric field behavior, production, and destruction pathways of dominant radical species. We find that higher relative permittivity promotes propagation of electric field and formation of conduction channel in the plasma column. The streamer discharge is sustained by the direct electron-impact ionization of methane molecule. Furthermore, the electron-impact dissociation of methane (e + CH4 = >e + H+CH3) is found to be the dominant reaction pathway to produce CH3 and H radicals. Similarly, the electron-impact dissociations of oxygen (e + O2 = >e + O+O(1D), e + O2 = >e + O+O) are the major routes for O production.