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Liquid-liquid equilibria: Verification of the lever rule

The mutual solubility curve for a binary system of partly miscible liquids is often constructed by determining the temperature at which a known composition of the mixture becomed homogeneous. Jordan describes an experiment that adds an alternate determination of the composition and mass of one of th...

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Bibliographic Details
Published in:Journal of chemical education 2000-03, Vol.77 (3), p.395
Main Author: Jordan, A D
Format: Article
Language:English
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Online Access:Get full text
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Summary:The mutual solubility curve for a binary system of partly miscible liquids is often constructed by determining the temperature at which a known composition of the mixture becomed homogeneous. Jordan describes an experiment that adds an alternate determination of the composition and mass of one of the layers in a known overall composition of a mixture and then comparing these values to those obtained at the same temperature and overall composition from the phase diagram.
ISSN:0021-9584
1938-1328
DOI:10.1021/ed077p395