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Vibrational Spectroscopic and Thermodynamic Investigation of Poly (vinyl butyral)

A detailed study was performed to investigate the normal modes of vibration and their dispersions in poly (vinyl butyral) by using Urey-Bradley force field and Wilson’s GF matrix method as modified by Higgs. It provides detailed interpretation of FTIR. Characteristic feature of dispersion curves suc...

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Published in:Oriental journal of chemistry 2016, Vol.32 (1), p.429-435
Main Authors: Ansari, Saiful, Ali, Parvej, Srivastava, Seema, Khan, Irfan
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Language:English
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creator Ansari, Saiful
Ali, Parvej
Srivastava, Seema
Khan, Irfan
description A detailed study was performed to investigate the normal modes of vibration and their dispersions in poly (vinyl butyral) by using Urey-Bradley force field and Wilson’s GF matrix method as modified by Higgs. It provides detailed interpretation of FTIR. Characteristic feature of dispersion curves such as regions of high density–of–states, repulsion and character mixing of dispersion modes are discussed. Predictive values of heat capacity as a function of temperature between 0-350 K have been evaluated.
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subjects Adhesives
Decomposition
Dispersion curve analysis
Energy
Heat
Microscopy
Polymers
Polyvinyl butyral
Spectrum analysis
Vibration mode
title Vibrational Spectroscopic and Thermodynamic Investigation of Poly (vinyl butyral)
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