Synthesis, Characterization and Crystal Structure Determination of a New Indium (III) Complex: [In(5,5’-DiMeBiPy)Cl3(DMSO)].2(DMSO)

[In(5,5’-DiMeBiPy)Cl3(DMSO)].2(DMSO) complex (5,5’-DiMeBiPy is 5,5’-Dimethyl-2,2’-bipyridine) was prepared from reaction of InCl3.4H2O with 5,5’-DiMeBiPy in 1.1 molar ratio in DMSO. This compound has been characterized by IR, 1H NMR, UV-Vis spectroscopy as well as X-ray crystallography. This compoun...

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Bibliographic Details
Published in:Oriental journal of chemistry 2014, Vol.30 (1), p.379-383
Main Authors: Shirvan, Sadif, Khazali, Fereydoon, Dezfuli, Sara
Format: Article
Language:English
Subjects:
Biochemistry
Chemistry
Chloride ions
Crystal structure
Crystallography
Data collection
Diffraction
Indium
Infrared spectroscopy
Ligands
Molecular structure
NMR
Nuclear magnetic resonance
Software
Structural analysis
Unit cell
Vibration
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Summary:[In(5,5’-DiMeBiPy)Cl3(DMSO)].2(DMSO) complex (5,5’-DiMeBiPy is 5,5’-Dimethyl-2,2’-bipyridine) was prepared from reaction of InCl3.4H2O with 5,5’-DiMeBiPy in 1.1 molar ratio in DMSO. This compound has been characterized by IR, 1H NMR, UV-Vis spectroscopy as well as X-ray crystallography. This compound crystallizes in the space group Pī of the triclinic system. The unit cell dimensions is: a = 8.6695(8) Å, b = 12.8456(14) Å, c = 13.0877(12) Å, a = 78.258(8)º, β = 85.270(8)º, g = 74.932(8)º. According to X-ray structure determination, there are one molecules of the complex and two DMSO solvent molecules in the asymmetric unit. In this complex the geometry at the indium (III) center is octahedral, formed by two nitrogen atom of 5,5’-DiMeBiPy ligand, three chloride ions and one DMSO molecule in trans position to chloride ion.
ISSN:0970-020X
2231-5039
DOI:10.13005/ojc/300154