A mobile system for a comprehensive online-characterization of nanoparticle aggregates based on wide-angle light scattering and laser-induced incandescence

• Published in: Review of scientific instruments 2016-05, Vol.87 (5), p.053102-053102
• Main Authors: Huber, Franz J. T., Altenhoff, Michael, Will, Stefan
• Format: Article
• Language: English
• Subjects: AEROSOL GENERATORS; AEROSOLS; Aggregates; Angular resolution; CAMERAS; CHARGE-COUPLED DEVICES; COMBUSTION; Dilution; ELECTRONS; Industrial applications; INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; Laser beam heating; Laser induced incandescence; Lasers; LIGHT SCATTERING; LIGHT SOURCES; Measurement techniques; NANOPARTICLES; NEODYMIUM LASERS; On-line systems; Optical measurement; Particle decay; PARTICLE PROPERTIES; PARTICLE SIZE; Photomultiplier tubes; PHOTOMULTIPLIERS; PROCESS CONTROL; Process controls; Product development; PULSES; Scientific apparatus & instruments; Semiconductor lasers; SIGNALS; Soot; THERMAL RADIATION; TIME RESOLUTION; TRANSMISSION ELECTRON MICROSCOPY; YAG lasers
• ISSN: 0034-6748; 1089-7623
• DOI: 10.1063/1.4948288

A mobile demonstrator for the comprehensive online-characterization of gas-borne nanoparticle aggregates is presented. Two optical measurement techniques are combined, both utilizing a pulsed Nd:YAG laser as light source. Aggregate size and fractal dimension are measured by Wide-Angle Light Scattering (WALS). An ellipsoidal mirror images elastically scattered light from scattering angles between 10° and 165° onto a CCD-camera chip resulting in an almost complete scattering diagram with high angular resolution. Primary particle size and volume fraction are measured by time-resolved Laser-Induced Incandescence (TiRe-LII). Here, particles are heated up to about 3000 K by the short laser pulse, the enhanced thermal radiation signal is detected with gated photomultiplier tubes. Analysis of the signal decay time and maximum LII-signal allows for the determination of primary particle diameter and volume fraction. The performance of the system is demonstrated by combined measurements on soot nanoparticle aggregates from a soot aerosol generator. Particle and aggregate sizes are varied by using different equivalence ratios of the combustion in the generator. Soot volume fraction can be adjusted by different levels of dilution with air. Online-measurements were carried out demonstrating the favorable performance of the system and the potential for industrial applications such as process control and product development. The particle properties obtained are confirmed through transmission electron microscopy analysis on representative samples.