Use of rhodamine-allyl Schiff base in chemodosimetric processes for total palladium estimation and application in live cell imaging

Rhodamine derivatives are excellent fluorescent probes and have shown sharp descending trends of emission intensity on interaction with specific analytes, which causes opening of the spirolactam ring. In this study, rhodamine-allyl Schiff base ( RD-2 ) is used as a highly sensitive colorimetric and...

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Published in:New journal of chemistry 2018, Vol.42 (21), p.17351-17358
Main Authors: Bhanja, Anup Kumar, Mishra, Snehasis, Kar, Ketaki, Naskar, Kaushik, Maity, Suvendu, Das Saha, Krishna, Sinha, Chittaranjan
Format: Article
Language:English
Subjects:
Carbon 13
Chemical sensors
Chemoreceptors
Colorimetry
Crystal structure
Crystallography
Diffraction
Emission analysis
Fluorescent indicators
Imines
NMR
Nuclear magnetic resonance
Oxidation
Palladium
Rhodamine
Single crystals
X ray powder diffraction
X-ray diffraction
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cited_by cdi_FETCH-LOGICAL-c259t-b5731a013e280c8b734a29ddb9eaa1749e7411710a13efeb59d6297b72e300cf3
cites cdi_FETCH-LOGICAL-c259t-b5731a013e280c8b734a29ddb9eaa1749e7411710a13efeb59d6297b72e300cf3
container_end_page 17358
container_issue 21
container_start_page 17351
container_title New journal of chemistry
container_volume 42
creator Bhanja, Anup Kumar
Mishra, Snehasis
Kar, Ketaki
Naskar, Kaushik
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Sinha, Chittaranjan
description Rhodamine derivatives are excellent fluorescent probes and have shown sharp descending trends of emission intensity on interaction with specific analytes, which causes opening of the spirolactam ring. In this study, rhodamine-allyl Schiff base ( RD-2 ) is used as a highly sensitive colorimetric and fluorescent chemosensor for total palladium determination, and is indifferent to oxidation states (0, ii , iv ). The LOD is 95 nM. In addition, it is also a brilliant sensor for in vitro imaging of Pd 2+ in RAW 264.7 (macrophage) cells. The probe RD-2 is structurally characterised by single-crystal X-ray diffraction measurement.
doi_str_mv 10.1039/C8NJ04519D
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Carbon 13
Chemical sensors
Chemoreceptors
Colorimetry
Crystal structure
Crystallography
Diffraction
Emission analysis
Fluorescent indicators
Imines
NMR
Nuclear magnetic resonance
Oxidation
Palladium
Rhodamine
Single crystals
X ray powder diffraction
X-ray diffraction
title Use of rhodamine-allyl Schiff base in chemodosimetric processes for total palladium estimation and application in live cell imaging
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