Non‐Pairwise Interactions in Parahydrogen Experiments: Nuclear Exchange of Single Protons Enables Bulk Water Hyperpolarization

The front cover artwork is provided by Dr. Meike Emondts, Daniel Schikowski, and Prof. Dr. Jürgen Klankermayer (RWTH Aachen University, Germany) as well as by Dr. Philipp Schleker (MPI CEC and FZJ, Germany). The image shows the hyperpolarization of HDO via the new NEPTUN mechanism describing a chemi...

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Bibliographic Details
Published in:Chemphyschem 2018-10, Vol.19 (20), p.2602-2602
Main Authors: Emondts, Meike, Schikowski, Daniel, Klankermayer, Jürgen, Schleker, P. Philipp M.
Format: Article
Language:English
Subjects:
Exchanging
Metathesis
Organic chemistry
Online Access:Get full text
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Summary:The front cover artwork is provided by Dr. Meike Emondts, Daniel Schikowski, and Prof. Dr. Jürgen Klankermayer (RWTH Aachen University, Germany) as well as by Dr. Philipp Schleker (MPI CEC and FZJ, Germany). The image shows the hyperpolarization of HDO via the new NEPTUN mechanism describing a chemical exchange/metathesis reaction between D2O and parahydrogen. Read the full text of the Communication at 10.1002/cphc.201800521. “The mechanism of bulk water hyperpolarization is investigated with a combination of theoretical and experimental methods, showing a chemical exchange pathway of single protons as a basis for the enhancement …” This and more about the story behind the front cover can be found in the Communication at 10.1002/cphc.201800521.
ISSN:1439-4235
1439-7641
DOI:10.1002/cphc.201800840