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Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions
We have investigated the effect of ferroelectric barium titanate (BaTiO3) film thickness on the charge transport mechanism in pulsed laser deposited epitaxial metal–ferroelectric semiconductor junctions. The current (I)–voltage (V) measurements across the junctions comprising of 20–500 nm thick BaTi...
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Published in: | Journal of applied physics 2015-09, Vol.118 (11) |
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creator | Singh, Pooja Rout, P. K. Singh, Manju Rakshit, R. K. Dogra, Anjana |
description | We have investigated the effect of ferroelectric barium titanate (BaTiO3) film thickness on the charge transport mechanism in pulsed laser deposited epitaxial metal–ferroelectric semiconductor junctions. The current (I)–voltage (V) measurements across the junctions comprising of 20–500 nm thick BaTiO3 and conducting bottom electrode (Nb: SrTiO3 substrate or La2/3Ca1/3MnO3 buffer layer) demonstrate the space charge limited conduction. Further analysis indicates a reduction in the ratio of free to trapped carriers with increasing thickness in spite of decreasing trap density. Such behaviour arises the deepening of the shallow trap levels ( |
doi_str_mv | 10.1063/1.4931158 |
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K. ; Singh, Manju ; Rakshit, R. K. ; Dogra, Anjana</creator><creatorcontrib>Singh, Pooja ; Rout, P. K. ; Singh, Manju ; Rakshit, R. K. ; Dogra, Anjana</creatorcontrib><description>We have investigated the effect of ferroelectric barium titanate (BaTiO3) film thickness on the charge transport mechanism in pulsed laser deposited epitaxial metal–ferroelectric semiconductor junctions. The current (I)–voltage (V) measurements across the junctions comprising of 20–500 nm thick BaTiO3 and conducting bottom electrode (Nb: SrTiO3 substrate or La2/3Ca1/3MnO3 buffer layer) demonstrate the space charge limited conduction. Further analysis indicates a reduction in the ratio of free to trapped carriers with increasing thickness in spite of decreasing trap density. Such behaviour arises the deepening of the shallow trap levels (<0.65 eV) below conduction band with increasing thickness. Moreover, the observed hysteresis in I–V curves implies a bipolar resistive switching behaviour, which can be explained in terms of charge trapping and de-trapping process.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.4931158</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Applied physics ; Barium titanates ; Buffer layers ; Charge transport ; Conduction bands ; Ferroelectric materials ; Ferroelectricity ; Film thickness ; Heterojunctions ; Pulsed laser deposition ; Pulsed lasers ; Semiconductor junctions ; Space charge ; Strontium titanates ; Substrates ; Trapping</subject><ispartof>Journal of applied physics, 2015-09, Vol.118 (11)</ispartof><rights>2015 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c323t-65eace5dda04bee96450253db3b6d080c78b3492b83ffd7641fb96b948fd58003</citedby><cites>FETCH-LOGICAL-c323t-65eace5dda04bee96450253db3b6d080c78b3492b83ffd7641fb96b948fd58003</cites><orcidid>0000-0001-6362-939X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Singh, Pooja</creatorcontrib><creatorcontrib>Rout, P. K.</creatorcontrib><creatorcontrib>Singh, Manju</creatorcontrib><creatorcontrib>Rakshit, R. K.</creatorcontrib><creatorcontrib>Dogra, Anjana</creatorcontrib><title>Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions</title><title>Journal of applied physics</title><description>We have investigated the effect of ferroelectric barium titanate (BaTiO3) film thickness on the charge transport mechanism in pulsed laser deposited epitaxial metal–ferroelectric semiconductor junctions. The current (I)–voltage (V) measurements across the junctions comprising of 20–500 nm thick BaTiO3 and conducting bottom electrode (Nb: SrTiO3 substrate or La2/3Ca1/3MnO3 buffer layer) demonstrate the space charge limited conduction. Further analysis indicates a reduction in the ratio of free to trapped carriers with increasing thickness in spite of decreasing trap density. Such behaviour arises the deepening of the shallow trap levels (<0.65 eV) below conduction band with increasing thickness. Moreover, the observed hysteresis in I–V curves implies a bipolar resistive switching behaviour, which can be explained in terms of charge trapping and de-trapping process.</description><subject>Applied physics</subject><subject>Barium titanates</subject><subject>Buffer layers</subject><subject>Charge transport</subject><subject>Conduction bands</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Film thickness</subject><subject>Heterojunctions</subject><subject>Pulsed laser deposition</subject><subject>Pulsed lasers</subject><subject>Semiconductor junctions</subject><subject>Space charge</subject><subject>Strontium titanates</subject><subject>Substrates</subject><subject>Trapping</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNotkL1OwzAURi0EEqUw8AaWmBhSrmM7sUeo-JMidSlzFNvXNKXYwXYH3p6idvqWo-9Ih5BbBgsGDX9gC6E5Y1KdkRkDpatWSjgnM4CaVUq3-pJc5bwFYExxPSPdejPar4A5U4cTBoehULsZ0ifSkoaQp5gKHQP1mFLEHdqSRkufhvW44nSDBVPc7oMtYwz5mlz4YZfx5rRz8vHyvF6-Vd3q9X352FWW17xUjcTBonRuAGEQdSMk1JI7w03jQIFtleFC10Zx713bCOaNbowWyjupAPic3B1_pxR_9phLv437FA7Kvma1AN1yUR-o-yNlU8w5oe-nNH4P6bdn0P_H6ll_isX_AN3MW_0</recordid><startdate>20150921</startdate><enddate>20150921</enddate><creator>Singh, Pooja</creator><creator>Rout, P. K.</creator><creator>Singh, Manju</creator><creator>Rakshit, R. K.</creator><creator>Dogra, Anjana</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6362-939X</orcidid></search><sort><creationdate>20150921</creationdate><title>Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions</title><author>Singh, Pooja ; Rout, P. K. ; Singh, Manju ; Rakshit, R. K. ; Dogra, Anjana</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-65eace5dda04bee96450253db3b6d080c78b3492b83ffd7641fb96b948fd58003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Applied physics</topic><topic>Barium titanates</topic><topic>Buffer layers</topic><topic>Charge transport</topic><topic>Conduction bands</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Film thickness</topic><topic>Heterojunctions</topic><topic>Pulsed laser deposition</topic><topic>Pulsed lasers</topic><topic>Semiconductor junctions</topic><topic>Space charge</topic><topic>Strontium titanates</topic><topic>Substrates</topic><topic>Trapping</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Pooja</creatorcontrib><creatorcontrib>Rout, P. K.</creatorcontrib><creatorcontrib>Singh, Manju</creatorcontrib><creatorcontrib>Rakshit, R. K.</creatorcontrib><creatorcontrib>Dogra, Anjana</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Pooja</au><au>Rout, P. K.</au><au>Singh, Manju</au><au>Rakshit, R. K.</au><au>Dogra, Anjana</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions</atitle><jtitle>Journal of applied physics</jtitle><date>2015-09-21</date><risdate>2015</risdate><volume>118</volume><issue>11</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>We have investigated the effect of ferroelectric barium titanate (BaTiO3) film thickness on the charge transport mechanism in pulsed laser deposited epitaxial metal–ferroelectric semiconductor junctions. The current (I)–voltage (V) measurements across the junctions comprising of 20–500 nm thick BaTiO3 and conducting bottom electrode (Nb: SrTiO3 substrate or La2/3Ca1/3MnO3 buffer layer) demonstrate the space charge limited conduction. Further analysis indicates a reduction in the ratio of free to trapped carriers with increasing thickness in spite of decreasing trap density. Such behaviour arises the deepening of the shallow trap levels (<0.65 eV) below conduction band with increasing thickness. Moreover, the observed hysteresis in I–V curves implies a bipolar resistive switching behaviour, which can be explained in terms of charge trapping and de-trapping process.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4931158</doi><orcidid>https://orcid.org/0000-0001-6362-939X</orcidid></addata></record> |
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subjects | Applied physics Barium titanates Buffer layers Charge transport Conduction bands Ferroelectric materials Ferroelectricity Film thickness Heterojunctions Pulsed laser deposition Pulsed lasers Semiconductor junctions Space charge Strontium titanates Substrates Trapping |
title | Thickness dependent charge transport in ferroelectric BaTiO3 heterojunctions |
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