Single crystal growth, structural, morphological & Raman tensor studies of [ZnCl4]− [C5H8N2Cl]+ hybrid material

The single crystal synthesis of 2-amino-5-chloropyridine tetrachlorozincate(II) through physical secondary interaction route has been performed by solution growth (SG)-slow cooling (SC) and Gel-crystal growth techniques. The crystal data and geometrical cell parameters of the hybrid material have be...

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Bibliographic Details
Format: Conference Proceeding
Language:English
Subjects:
Absorption spectra
Crystal growth
Crystal structure
Energy gap
Mathematical analysis
Morphology
Parameters
Single crystals
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Summary:The single crystal synthesis of 2-amino-5-chloropyridine tetrachlorozincate(II) through physical secondary interaction route has been performed by solution growth (SG)-slow cooling (SC) and Gel-crystal growth techniques. The crystal data and geometrical cell parameters of the hybrid material have been studied by XRD experimental and computational techniques. UV-Vis absorption spectra is used to calculate the energy band gap = 3.42 eV. The granular size and spatial morphological features such as circularity = 0.829, skew parameter = −0.137, etc were analyzed by SEM image. The Raman and Hyper-Raman tensor calculations based on XRD data were performed for hybrid materials.
ISSN:0094-243X
1551-7616
DOI:10.1063/1.4929199