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NbS3: A unique quasi-one-dimensional conductor with three charge density wave transitions

We review the features of the charge density wave (CDW) conductor NbS3 (phase II) and include several additional results from transport, compositional, and structural studies. Particularly, we highlight three central results: (1) In addition to the previously reported CDW transitions at TP1=360K and...

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Bibliographic Details
Published in:Physical review. B 2017-01, Vol.95 (3), p.035110
Main Authors: Zybtsev, S G, Pokrovskii, V Ya, Nasretdinova, V F, Zaitsev-Zotov, S V, Pavlovskiy, V Pavlovskiy, Odobesco, A B, Pai, Woei Wu, Chu, M-W, Lin, Y G, Zupanič, E, van Midden, H J P, Šturm, S, Tchernychova, E, Prodan, A, Bennett, J C, Mukhamedshin, I R, Chernysheva, O V, Menushenkov, A P, Loginov, V B, Loginov, B A, Titov, A N, Abdel-Hafiez, M
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Language:English
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Summary:We review the features of the charge density wave (CDW) conductor NbS3 (phase II) and include several additional results from transport, compositional, and structural studies. Particularly, we highlight three central results: (1) In addition to the previously reported CDW transitions at TP1=360K and TP2=150K, a third CDW transition occurs at a much higher temperature TP0≈620−650K; evidence for the nonlinear conductivity of this CDW is presented. (2) We show that the CDW associated with the TP2 transition arises from S vacancies acting as donors. Such a CDW transition has not been observed before. (3) We demonstrate the exceptional coherence of the TP1 CDW at room temperature. The effects of uniaxial strain on the CDW transition temperature and transport are reported.
ISSN:2469-9950
2469-9969
DOI:10.1103/PhysRevB.95.035110