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Bulk and domain-wall effects in ferroelectric photovoltaics
We investigate the photovoltaic (PV) effects in ferroelectrics based on the polar structure in domains and the intrinsic symmetry breaking of ferroelastic domain walls (DWs). A comprehensive analysis for BiFeO3 films with the single-domain and 71° domain structures reveals a major contribution of th...
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Published in: | Physical review. B 2016-12, Vol.94 (21), Article 214111 |
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container_title | Physical review. B |
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creator | Matsuo, Hiroki Kitanaka, Yuuki Inoue, Ryotaro Noguchi, Yuji Miyayama, Masaru Kiguchi, Takanori Konno, Toyohiko J. |
description | We investigate the photovoltaic (PV) effects in ferroelectrics based on the polar structure in domains and the intrinsic symmetry breaking of ferroelastic domain walls (DWs). A comprehensive analysis for BiFeO3 films with the single-domain and 71° domain structures reveals a major contribution of the DWs superimposed on the bulk PV effect, which can explain the enhanced PV response in the multidomain film exhibiting photovoltages greater than the band gap. Our methodology can reveal the contributions of the bulk PV and the DW-PV effects quantitatively and uncover a design strategy for enhancing ferroelectric photovoltaics. |
doi_str_mv | 10.1103/PhysRevB.94.214111 |
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subjects | Bismuth compounds Broken symmetry Domain walls Ferroelectric materials Ferroelectricity Photovoltages Photovoltaic cells Solar cells Wall effects |
title | Bulk and domain-wall effects in ferroelectric photovoltaics |
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